Electrooxidation of COad intermediated from methanol oxidation on polycrystalline Pt electrode
文献类型：期刊论文
| 作者 | Xu WL ; Lu TH ; Liu CP ; Xing W |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2006 |
| 卷号 | 110期号:10页码:4802-4807 |
| 关键词 | NORMAL PULSE VOLTAMMETRY PLATINUM-ELECTRODE KINETICS COMPLEXES SURFACES POLAROGRAPHY POLYMERS FILM |
| ISSN号 | 1520-6106 |
| 通讯作者 | xing w |
| 中文摘要 | the poisonous intermediate of methanol oxidation on a pt electrode was validated to be coad by electrochemical method. an approximate treatment to bimolecular elementary reactions on an electrode was advanced and then was applied to the stripping normal pulse voltammetry (npv) for complex multistep multielectron transfer processes on plane electrodes to study the kinetics of completely irreversible process of coad oxidation to co2. the kinetic parameters for this process, such as standard rate constant (0) and anodic transfer coefficient (alpha) for this irreversible heterogeneous electron-transfer process at electrode/solution interface and apparent diffusion coefficient (d-app) for charge-transfer process within the monolayer of coad on electrode surface, were obtained with stripping npv method. the effect of the approximate treatment on the kinetic parameters was also analyzed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236077600046 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15991]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu WL,Lu TH,Liu CP,et al. Electrooxidation of COad intermediated from methanol oxidation on polycrystalline Pt electrode[J]. journal of physical chemistry b,2006,110(10):4802-4807. |
| APA | Xu WL,Lu TH,Liu CP,&Xing W.(2006).Electrooxidation of COad intermediated from methanol oxidation on polycrystalline Pt electrode.journal of physical chemistry b,110(10),4802-4807. |
| MLA | Xu WL,et al."Electrooxidation of COad intermediated from methanol oxidation on polycrystalline Pt electrode".journal of physical chemistry b 110.10(2006):4802-4807. |
入库方式： OAI收割
来源：长春应用化学研究所
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