Facile separation and determination of Aconitine alkaloids in traditional Chinese medicines by CE with tris(2,2 '-bipyridyl) ruthenium(II)-based electrochemi-luminescence detection
文献类型：期刊论文
| 作者 | Yin JY ; Guo WW ; Du Y ; Wang E |
| 刊名 | electrophoresis
 |
| 出版日期 | 2006 |
| 卷号 | 27期号:23页码:4836-4841 |
| 关键词 | PERFORMANCE LIQUID-CHROMATOGRAPHY CAPILLARY-ELECTROPHORESIS URINE SAMPLES HERBS BLOOD |
| ISSN号 | 0173-0835 |
| 通讯作者 | wang ek |
| 中文摘要 | a facile ce method coupled with tris(2,2'-bipyridyl) ruthenium(ll)-based electrochem iluminescence [ru(bpy)(3)(2+)] detection was developed for simultaneous determination of aconitum alkaloids, i.e., hypaconitine (ha), aconitine (ac), and mesaconitine (ma) in baseline separation. the optimal separation of these aconitum alkaloids was achieved in a fused-silica capillary column (50 cm x 25 mu m id) with 30 mm phosphate solution (ph 8.40) as running buffer at 12 kv applied voltage. the three alkaloids can be determined within 10 min by a single run. the calibration curves showed a linear range from 2.0 x 10(-7) to 2.0 x 10(-5) m for ha, 3.4 x 10(-7) to 1.7 x 10(-5) m for ac, and 3.8 x 10(-7) to 1.9 x 10(-5) m for ma. the rsds; for all analytes were below 3.01%. good linear relationships were found with correlation coefficients for all analytes exceeding 0.993. the detection limits were 2.0 x 10(-8) m for ha, 1.7 x 10(-7) m for ac, and 1.9 x 10(-7) m for ma under optimal conditions. this method was successfully applied to determine the three alkaloids in aconitum plants. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242903000027 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16029]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yin JY,Guo WW,Du Y,et al. Facile separation and determination of Aconitine alkaloids in traditional Chinese medicines by CE with tris(2,2 '-bipyridyl) ruthenium(II)-based electrochemi-luminescence detection[J]. electrophoresis,2006,27(23):4836-4841. |
| APA | Yin JY,Guo WW,Du Y,&Wang E.(2006).Facile separation and determination of Aconitine alkaloids in traditional Chinese medicines by CE with tris(2,2 '-bipyridyl) ruthenium(II)-based electrochemi-luminescence detection.electrophoresis,27(23),4836-4841. |
| MLA | Yin JY,et al."Facile separation and determination of Aconitine alkaloids in traditional Chinese medicines by CE with tris(2,2 '-bipyridyl) ruthenium(II)-based electrochemi-luminescence detection".electrophoresis 27.23(2006):4836-4841. |
入库方式： OAI收割
来源：长春应用化学研究所
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