Syntheses of fully sulfonated polyaniline nano-networks and its application to the direct electrochemistry of cytochrome c
文献类型：期刊论文
| 作者 | Zhang L ; Jiang X ; Niu L ; Dong SJ |
| 刊名 | biosensors & bioelectronics
 |
| 出版日期 | 2006 |
| 卷号 | 21期号:7页码:1107-1115 |
| 关键词 | FERRICYTOCHROME-C DOPED POLYANILINE GOLD ELECTRODES HORSE ACID PROTEINS ANILINE GROWTH POLYMERIZATION REDUCTION |
| ISSN号 | 0956-5663 |
| 通讯作者 | dong sj |
| 中文摘要 | fully sulfonated polyaniline nano-particles, nano-fibrils and nano-networks have been achieved for the first time by electrochemical homopolymerization of orthanilic acid using a three-step electrochemical deposition procedure in a mixed solvent of acetonitrile (acn) and water. the diameter of the uniform nano-particles is about 60nm, and the nano-fibrils can be organized in two-dimensional (21)) or three-dimensional (313) non-periodic networks with good electrical contact. average distance between contacts is about 850 and 600 nm for a 2d and 3d system, respectively. the details of the poly(orthanilic acid) (poa) nano-structure were examined with a field emission scanning electron microscope (sem). the structure and properties of poa were characterized with ftir, uv-vis and electrochemical methods. the 3d poa nano-networks coated platinum electrode gave a direct electrochemical behavior of horse heart cytochrome c (cyt c) immobilized on this electrode surface, a pair of well-defined redox waves with formal potential (e-ol) of -0.032 v (versus ag/agcl) was achieved. the interaction between cyt c and poa makes the formal potential shift negatively compared to that of cyt c in solution. spectrophotometric and electrochemical methods were used to investigate the interaction of cyt c with poa. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000234644400015 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16079]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang L,Jiang X,Niu L,et al. Syntheses of fully sulfonated polyaniline nano-networks and its application to the direct electrochemistry of cytochrome c[J]. biosensors & bioelectronics,2006,21(7):1107-1115. |
| APA | Zhang L,Jiang X,Niu L,&Dong SJ.(2006).Syntheses of fully sulfonated polyaniline nano-networks and its application to the direct electrochemistry of cytochrome c.biosensors & bioelectronics,21(7),1107-1115. |
| MLA | Zhang L,et al."Syntheses of fully sulfonated polyaniline nano-networks and its application to the direct electrochemistry of cytochrome c".biosensors & bioelectronics 21.7(2006):1107-1115. |
入库方式： OAI收割
来源：长春应用化学研究所
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