A nonmonotonic dependence of standard rate constant on reorganization energy for heterogeneous electron transfer processes on electrode surface
文献类型：期刊论文
| 作者 | Xu WL ; Li ST ; Zhou XC ; Xing W ; Huang MY ; Lu TH ; Liu CP |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2006 |
| 卷号 | 124期号:17页码:文献编号：174706 |
| 关键词 | LIQUID/LIQUID INTERFACE LIQUID INTERFACES INVERTED REGION CHARGE-TRANSFER MARCUS THEORY OUTER-SPHERE OXIDATION SOLVENT TRANSITIONS MONOLAYER |
| ISSN号 | 0021-9606 |
| 通讯作者 | xing w |
| 中文摘要 | in the present work a nonmonotonic dependence of standard rate constant (k(0)) on reorganization energy (lambda) was discovered qualitatively from electron transfer (marcus-hush-levich) theory for heterogeneous electron transfer processes on electrode surface. it was found that the nonmonotonic dependence of k(0) on lambda is another result, besides the disappearance of the famous marcus inverted region, coming from the continuum of electronic states in electrode: with the increase of lambda, the states for both process i and process ii et processes all vary from nonadiabatic to adiabatic state continuously, and the lambda dependence of k(0) for process i is monotonic thoroughly, while for process ii on electrode surface the lambda dependence of k(0) could show a nonmonotonicity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000237321700031 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16113]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu WL,Li ST,Zhou XC,et al. A nonmonotonic dependence of standard rate constant on reorganization energy for heterogeneous electron transfer processes on electrode surface[J]. journal of chemical physics,2006,124(17):文献编号：174706. |
| APA | Xu WL.,Li ST.,Zhou XC.,Xing W.,Huang MY.,...&Liu CP.(2006).A nonmonotonic dependence of standard rate constant on reorganization energy for heterogeneous electron transfer processes on electrode surface.journal of chemical physics,124(17),文献编号：174706. |
| MLA | Xu WL,et al."A nonmonotonic dependence of standard rate constant on reorganization energy for heterogeneous electron transfer processes on electrode surface".journal of chemical physics 124.17(2006):文献编号：174706. |
入库方式： OAI收割
来源：长春应用化学研究所
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