Dibenzyl trithiocarbonate mediated reversible addition-fragmentation chain transfer polymerization of acrylonitrile
文献类型：期刊论文
| 作者 | Liu XH ; Zhang GB ; Lu XF ; Liu JY ; Pan D ; Li YS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 44期号:1页码:490-498 |
| 关键词 | TRANSFER RADICAL POLYMERIZATION TRANSFER RAFT POLYMERIZATION SEEDED EMULSION POLYMERIZATION TRANSFER AGENT LEAVING GROUPS COPOLYMERS KINETICS INITIALIZATION ARCHITECTURES STYRENE |
| ISSN号 | 0887-624x |
| 通讯作者 | li ys |
| 中文摘要 | reversible addition-fragmentation chain transfer polymerization has been successfully applied to polymerize acrylonitrile with dibenzyl trithiocarbonate as the chain-transfer agent. the key to success is ascribed to the improvement of the interchange frequency between dormant and active species through the reduction of the activation energy for the fragmentation of the intermediate. the influence of several experimental parameters, such as the molar ratio of the chain-transfer agent to the initiator [azobis(isobutyronitrile)], the molar ratio of the monomer to the chain-transfer agent, and the monomer concentration, on the polymerization kinetics and the molecular weight as well as the polydispersity has been investigated in detail. matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and h-1 nmr analyses have confirmed the chain-end functionality of the resultant polymer. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000234091800048 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16145]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XH,Zhang GB,Lu XF,et al. Dibenzyl trithiocarbonate mediated reversible addition-fragmentation chain transfer polymerization of acrylonitrile[J]. journal of polymer science part a-polymer chemistry,2006,44(1):490-498. |
| APA | Liu XH,Zhang GB,Lu XF,Liu JY,Pan D,&Li YS.(2006).Dibenzyl trithiocarbonate mediated reversible addition-fragmentation chain transfer polymerization of acrylonitrile.journal of polymer science part a-polymer chemistry,44(1),490-498. |
| MLA | Liu XH,et al."Dibenzyl trithiocarbonate mediated reversible addition-fragmentation chain transfer polymerization of acrylonitrile".journal of polymer science part a-polymer chemistry 44.1(2006):490-498. |
入库方式： OAI收割
来源：长春应用化学研究所
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