Preparation of linear alpha-olefins to high-molecular weight polyethylenes using cationic alpha-diimine nickel(II) complexes containing chloro-substituted ligands
文献类型：期刊论文
| 作者 | Song CL ; Tang LM ; Li YG ; Li XF ; Chen J ; Li YS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 44期号:6页码:1964-1974 |
| 关键词 | SUBSTITUTED 2 TRANSITION-METAL-COMPLEXES ETHYLENE HOMOPOLYMERIZATION (ALPHA-DIIMINE)NICKEL(II) CATALYSTS POLYMERIZATION CATALYSTS BRANCHED POLYETHYLENE COBALT COMPLEXES OLIGOMERIZATION COPOLYMERIZATION COORDINATION 6-BIS(IMINO)PYRIDYL IRON |
| ISSN号 | 0887-624x |
| 通讯作者 | li ys |
| 中文摘要 | a series of alpha-diimine nickel(ii) complexes containing chloro-substituted ligands, [(ar)n=c(c10h6)c=n(ar)]nibr2 (4a, ar = 2,3-c6h3cl2; 4b, ar = 2,4-c6h3cl2; 4c, ar = 2,5-c6h3cl2; 4d, ar = 2,6-c6h3cl2; 4e, ar = 2,4,6-c6h2cl3) and [(ar)n=c(c10h6)c=n(ar)](2)nibr2 (5a, ar = 2,3-c6h3cl2; 5b, ar = 2,4-c6h3cl2; 5c, ar = 2,5-c6h3cl2), have been synthesized and investigated as precatalysts for ethylene polymerization. in the presence of modified methylaluminoxane (mmao) as a cocatalyst, these complexes are highly effective catalysts for the oligomerization or polymerization of ethylene under mild conditions. the catalyst activity and the properties of the products were strongly affected by the aryl-substituents of the ligands used. depending on the catalyst structure, it is possible to obtain the products ranging from linear alpha-olefins to high-molecular weight polyethylenes. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235727600016 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16147]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Song CL,Tang LM,Li YG,et al. Preparation of linear alpha-olefins to high-molecular weight polyethylenes using cationic alpha-diimine nickel(II) complexes containing chloro-substituted ligands[J]. journal of polymer science part a-polymer chemistry,2006,44(6):1964-1974. |
| APA | Song CL,Tang LM,Li YG,Li XF,Chen J,&Li YS.(2006).Preparation of linear alpha-olefins to high-molecular weight polyethylenes using cationic alpha-diimine nickel(II) complexes containing chloro-substituted ligands.journal of polymer science part a-polymer chemistry,44(6),1964-1974. |
| MLA | Song CL,et al."Preparation of linear alpha-olefins to high-molecular weight polyethylenes using cationic alpha-diimine nickel(II) complexes containing chloro-substituted ligands".journal of polymer science part a-polymer chemistry 44.6(2006):1964-1974. |
入库方式： OAI收割
来源：长春应用化学研究所
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