Crosslinkable poly(propylene carbonate): High-yield synthesis and performance improvement
文献类型：期刊论文
| 作者 | Tao YH ; Wang XH ; Zhao XJ ; Li J ; Wang FS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 44期号:18页码:5329-5336 |
| 关键词 | ALLYL GLYCIDYL ETHER PROPYLENE-OXIDE ALTERNATING COPOLYMERIZATION FUNCTIONAL POLYCARBONATES POLY(BUTYLENE SUCCINATE) COORDINATION CATALYST NETWORK FORMATION DIOXIDE CO2 LINKING |
| ISSN号 | 0887-624x |
| 通讯作者 | wang xh |
| 中文摘要 | a crosslinking strategy was used to improve the thermal and mechanical performance of poly(propylene carbonate) (ppc): ppc bearing a small moiety of pendant c=c groups was synthesized by the terpolymerization of allyl glycidyl ether (age), propylene oxide (po), and carbon dioxide (co2). almost no yield loss was found in comparison with that of the po and co2 copolymer when the concentration of age units in the terpolymer was less than 5 mol %. once subjected to uv-radiation crosslinking, the crosslinked ppc film showed an elastic modulus 1 order of magnitude higher than that of the uncrosslinked one. moreover, crosslinked ppc showed hot-set elongation at 65 degrees c of 17.2% and permanent deformation approaching 0, whereas they were 35.3 and 17.2% for uncrosslinked ppc, respectively. therefore, the ppc application window was enlarged to a higher temperature zone by the crosslinking strategy. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000240300200009 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16159]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tao YH,Wang XH,Zhao XJ,et al. Crosslinkable poly(propylene carbonate): High-yield synthesis and performance improvement[J]. journal of polymer science part a-polymer chemistry,2006,44(18):5329-5336. |
| APA | Tao YH,Wang XH,Zhao XJ,Li J,&Wang FS.(2006).Crosslinkable poly(propylene carbonate): High-yield synthesis and performance improvement.journal of polymer science part a-polymer chemistry,44(18),5329-5336. |
| MLA | Tao YH,et al."Crosslinkable poly(propylene carbonate): High-yield synthesis and performance improvement".journal of polymer science part a-polymer chemistry 44.18(2006):5329-5336. |
入库方式： OAI收割
来源：长春应用化学研究所
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