Sol-gel synthesis and photoluminescence properties of spherical SiO2@LaPO4 : Ce3+/Tb3+ particles with a core-shell structure
文献类型:期刊论文
作者 | Yu M ; Wang H ; Lin CK ; Li GZ ; Lin J |
刊名 | nanotechnology
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出版日期 | 2006 |
卷号 | 17期号:13页码:3245-3252 |
关键词 | FIELD-EMISSION DISPLAYS SILICA SPHERES CORE/SHELL NANOPARTICLES SPRAY-PYROLYSIS ENERGY-TRANSFER THIN-FILMS PHOSPHORS MONODISPERSE NANOCRYSTALS COLLOIDS |
ISSN号 | 0957-4484 |
通讯作者 | lin j |
中文摘要 | lapo4: ce3+ and lapo4: ce3+, tb3+ phosphor layers have been deposited successfully on monodispersed and spherical sio2 particles of different sizes ( 300, 500, 900 and 1200 nm) through a sol - gel process, resulting in the formation of core - shell structured sio2@ lapo4: ce3+/ tb3+ particles. x-ray diffraction (xrd), fourier transform infrared spectroscopy (ft-ir), scanning electron microcopy (sem), transmission electron microscopy (tem), and general and time-resolved photoluminescence (pl) spectra as well as lifetimes were used to characterize the resulting sio2@ lapo4: ce3+/ tb3+ samples. the xrd results demonstrate that the lapo4: ce3+, tb3+ layers begin to crystallize on the sio2 templates after annealing at 700 degrees c, and the crystallinity increases on raising the annealing temperature. the obtained core - shell phosphors have perfectly spherical shape with a narrow size distribution, non-agglomeration, and a smooth surface. the doped rare-earth ions show their characteristic emission in the core - shell phosphors, i.e. ce3+ 5d - 4f and tb3+5d4 - f-7(j) (j = 6 - 3) transitions, respectively. the pl intensity of the tb3+ increased on increasing the annealing temperature and the sio2 core particle size. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000238259000028 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/16163] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Yu M,Wang H,Lin CK,et al. Sol-gel synthesis and photoluminescence properties of spherical SiO2@LaPO4 : Ce3+/Tb3+ particles with a core-shell structure[J]. nanotechnology,2006,17(13):3245-3252. |
APA | Yu M,Wang H,Lin CK,Li GZ,&Lin J.(2006).Sol-gel synthesis and photoluminescence properties of spherical SiO2@LaPO4 : Ce3+/Tb3+ particles with a core-shell structure.nanotechnology,17(13),3245-3252. |
MLA | Yu M,et al."Sol-gel synthesis and photoluminescence properties of spherical SiO2@LaPO4 : Ce3+/Tb3+ particles with a core-shell structure".nanotechnology 17.13(2006):3245-3252. |
入库方式: OAI收割
来源:长春应用化学研究所
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