中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents

文献类型:期刊论文

作者Liu F ; Wang Z ; Yang HL ; Gao LX ; Ding MX
刊名polymer
出版日期2006
卷号47期号:3页码:937-945
关键词BLEND MEMBRANES SLIDING WEAR POLYETHERIMIDE POLYMERS
ISSN号0032-3861
通讯作者wang z
中文摘要this paper reports the synthesis of a novel maleimide-terminated thioetherimide oligomer and its copolymefization with reactive solvents bearing vinyl. starting from 3-chlorophthalic anhydride and 4-chlorophthalic anhydride, 2,2',3,3'-thiodiphenyl tertracaboxylic dianhydride (3,3'-tdpa) and 3,3',4,4'-thiodiphenyl tertracaboxylic dianhydride (4,4'-tdpa) were synthesized. thereby, a novel maleimide-terminated thioetherimide oligomer was prepared from. 3,3-tdpa, 4,4'-tdpa, 3,3'-dimethyl-4,4-diaminodiphenylmethane (dmmda) and maleic anhydride. binary and ternary copolymer resin were derived from corresponding binary and ternary homogeous solution consisting of thioetherimide oligomer, reactive solvent n-vinylpyrrolidone (nvp) or n,n'-dimethylacrylamide (dmaa) and divinylbenzene (dvb) as modifier, initiated either by gamma ray irradiation or by benzoyl peroxide (bpo). thermal and mechanical properties of copolymer resin are determined and compared in terms of the kind of reactive solvent, addition of modifier dvb. the effect of initiation approach on property of final copolymer resin were studied. phase separation and sub-transition of ternary copolymer resin induced by bpo are observed, which could be accounted for by thermal movement of dmaa molecules during thermal initiation.
收录类别SCI
语种英语
WOS记录号WOS:000234935900020
公开日期2010-08-17
源URL[http://ir.ciac.jl.cn/handle/322003/16207]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Liu F,Wang Z,Yang HL,et al. Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents[J]. polymer,2006,47(3):937-945.
APA Liu F,Wang Z,Yang HL,Gao LX,&Ding MX.(2006).Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents.polymer,47(3),937-945.
MLA Liu F,et al."Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents".polymer 47.3(2006):937-945.

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来源:长春应用化学研究所

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