Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends
文献类型:期刊论文
作者 | Shi D ; Hu GH ; Ke Z ; Li RKY ; Yin JH |
刊名 | polymer
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出版日期 | 2006 |
卷号 | 47期号:13页码:4659-4666 |
关键词 | LINEAR VISCOELASTIC BEHAVIOR SITU FORMED COPOLYMERS TIME SPECTRA RHEOLOGICAL PROPERTIES INTERFACIAL PROPERTIES EXPERIMENTAL RESPONSES REGULARIZATION METHOD DISCRETE RELAXATION ELECTRON-MICROSCOPY POLYETHYLENE |
ISSN号 | 0032-3861 |
通讯作者 | shi d |
中文摘要 | this paper deals with the dynamic rheological behavior of polypropylene/polyamide6 (pp/pa6) uncompatibilized blends and those compatibilized with a maleic anhydride grafted pp (pp/pp-g-mah/pa6). the terminal relaxation times of the blends predicted by the palierne emulsion model were compared with those obtained from experimental relaxation time spectra. the palierne model succeeded well in describing pp/pa6 uncompatibilized blends with relatively low dispersed phase contents (10 wt%) and failed doing so for those of which the dispersed contents were high (30 wt%). it also failed for the compatibilized ones, irrespective of the dispersed phase content (10 or 30 wt%) and whether or not interface relaxation was taken into consideration. in the case of the uncompatibilized blend with high dispersed-phase content, interconnections among inclusions of the dispersed phase were responsible for the failure of the palierne model. as for the compatiblized blends, in addition to particle interconnections, the existence of emulsion-in-emulsion (ee) structures was another factor responsible for the failure of palieme model. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000238921300026 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/16221] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Shi D,Hu GH,Ke Z,et al. Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends[J]. polymer,2006,47(13):4659-4666. |
APA | Shi D,Hu GH,Ke Z,Li RKY,&Yin JH.(2006).Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends.polymer,47(13),4659-4666. |
MLA | Shi D,et al."Relaxation behavior of polymer blends with complex morphologies: Palierne emulsion model for uncompatibilized and compatibilized PP/PA6 blends".polymer 47.13(2006):4659-4666. |
入库方式: OAI收割
来源:长春应用化学研究所
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