Preparation of a carbon supported Pt catalyst using an improved organic sol method and its electrocatalytic activity for methanol oxidation
文献类型：期刊论文
| 作者 | Tang YW ; Zhang LL ; Wang YN ; Zhou YM ; Gao Y ; Liu CP ; Xing W ; Lu TH |
| 刊名 | journal of power sources
 |
| 出版日期 | 2006 |
| 卷号 | 162期号:1页码:124-131 |
| 关键词 | ULTRAFINE PLATINUM PARTICLES AIR FUEL-CELLS PT-RU ANODES ACID ELECTROLYTE OXYGEN REDUCTION AQUEOUS-SOLUTION SULFURIC-ACID CO TOLERANCE FORMIC-ACID ELECTROOXIDATION |
| ISSN号 | 0378-7753 |
| 通讯作者 | lu th |
| 中文摘要 | the organic sol method for preparing ultrafine transition metal colloid particles reported for the first time by bonnemann et al. [h. bonnemann, w brijoux, r. brinkmann, e. dinjus, t. jou beta en, b. korall, angew. chem. int. ed. engl., 30 (1991) 1312] has been improved in this paper. the improved organic sol method uses sncl2 as the reductant and methanol as the organic solvent. thus, this method is very simple and inexpensive. it was found that the average size of the pt particles in the pt/c catalysts can be controlled by adjusting the evaporating temperature of the solvent. therefore, the pt/c catalysts prepared by the same method are suitable for evaluating the size effect of the pt particles on electrocatalytic performance for methanol oxidation. the results of the x-ray diffraction (xrd) and transmission electron microscopy (tem) showed that when the evaporating temperatures of the solvent are 65, 60, 50, 40, and 30 degrees c, the average sizes of the pt particles in the pt/c catalysts prepared are: 2.2, 3.2, 3.8, 4.3, and 4.8 nm, respectively. the x-ray photoelectron spectroscopic (xps) results demonstrated that the small pt particles are easily oxidized and the decomposition/adsorption of methanol cannot proceed on the surfaces of pt oxides. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242059700014 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16241]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tang YW,Zhang LL,Wang YN,et al. Preparation of a carbon supported Pt catalyst using an improved organic sol method and its electrocatalytic activity for methanol oxidation[J]. journal of power sources,2006,162(1):124-131. |
| APA | Tang YW.,Zhang LL.,Wang YN.,Zhou YM.,Gao Y.,...&Lu TH.(2006).Preparation of a carbon supported Pt catalyst using an improved organic sol method and its electrocatalytic activity for methanol oxidation.journal of power sources,162(1),124-131. |
| MLA | Tang YW,et al."Preparation of a carbon supported Pt catalyst using an improved organic sol method and its electrocatalytic activity for methanol oxidation".journal of power sources 162.1(2006):124-131. |
入库方式： OAI收割
来源：长春应用化学研究所
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