Two new Cu-II coordination polymers: Studies of topological networks and water clusters
文献类型：期刊论文
| 作者 | Yang J ; Ma MF ; Liu YY ; Ma JC ; Jia HQ ; Hu NH |
| 刊名 | european journal of inorganic chemistry
 |
| 出版日期 | 2006 |
| 期号 | 6页码:1208-1215 |
| 关键词 | METAL-ORGANIC FRAMEWORK CHEMISTRY HYDRATION HEXAMERS COMPLEX RINGS CHAIN ACID NET |
| ISSN号 | 1434-1948 |
| 通讯作者 | ma mf |
| 中文摘要 | two new cull coordination polymers, namely [cu-2(bdc)(2)(l)(4)(h2o)(2)]center dot 14h(2)o (1) and [cu-1.5(btc)(l)(1.5)(h2o)(0.5)]center dot 2h(2)o (2), where l = 1,1'-(1,4-butanediyl)bis(imidazole), bdc = 1,4-benzene dicarboxylate, and btc = 1,3,5-benzenetricarboxylate, have been synthesized at room temperature. complex 1 exhibits an unusual, square-planar, four-connected 2d (2)(6)4 net, which has been predicated by wells. interestingly, three types of water clusters, namely (h2o)(6), (h2o)(8), and (h2o)(10), are observed in the hydrogen-bonded layers constructed by the bdc ligands and water molecules. the btc anion in compound 2 is coordinated to the cu" cation as tetradentate ligand to form a (6(6))(2)(4(2)6(4)8(4))(2)(6(4)810) net containing three kinds of nonequivalent points, thermogravimetric analyses (tga) and ir spectra for 1 and 2 are also discussed in detail. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236508700014 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16275]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang J,Ma MF,Liu YY,et al. Two new Cu-II coordination polymers: Studies of topological networks and water clusters[J]. european journal of inorganic chemistry,2006(6):1208-1215. |
| APA | Yang J,Ma MF,Liu YY,Ma JC,Jia HQ,&Hu NH.(2006).Two new Cu-II coordination polymers: Studies of topological networks and water clusters.european journal of inorganic chemistry(6),1208-1215. |
| MLA | Yang J,et al."Two new Cu-II coordination polymers: Studies of topological networks and water clusters".european journal of inorganic chemistry .6(2006):1208-1215. |
入库方式： OAI收割
来源：长春应用化学研究所
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