Silica supported submicron SiO2@Y2SiO5 : Eu3+ and SiO2@Y2SiO5 : Ce3+/Tb3+ spherical particles with a core-shell structure: Sol-gel synthesis and characterization
文献类型:期刊论文
作者 | Lin CK ; Wang H ; Kong DY ; Yu M ; Liu XM ; Wang ZL ; Lin J |
刊名 | european journal of inorganic chemistry
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出版日期 | 2006 |
期号 | 18页码:3667-3675 |
关键词 | NANOCRYSTALLINE THIN-FILMS FIELD-EMISSION DISPLAYS ENERGY-TRANSFER LUMINESCENCE PROPERTIES NANOMETRIC SCALE PHOTOLUMINESCENT PROPERTIES METALLORGANIC DECOMPOSITION SPECTROSCOPIC PROPERTIES QUANTUM EFFICIENCY MESOPOROUS SILICA |
ISSN号 | 1434-1948 |
通讯作者 | lin j |
中文摘要 | x-1-y(2)sio(5):eu3+ and x-1-y2sio5:ce3+ and/or tb3+ phosphor layers have been coated on nonaggregated, monodisperse, submicron spherical sio2 particles by a sol-gel process, followed by surface reaction at high temperature (1000 degrees c), to give core/shell structured sio2@y2sio5:eu3+ and sio2@y2sio5:ce3+/tb3+ particles. x-ray diffraction (xrd), field emission scanning electron microscopy (fesem), tem, photoluminescence (pl), low voltage cathodoluminescence (cl), and time-resolved pl spectra and lifetimes are used to characterize these materials. the xrd results indicate that x-1-y2sio5 layers have been successfully coated on the sur- face of sio2 particles, as further verified by the fesem and tem images. the pl and cl studies suggest that sio2@y2sio5:eu3+, sio2@y2sio5:tb3+ (or ce3+/tb3+), and sio2@y2sio5:ce3+ core/shell particles exhibit red (eu3+, 613 rim: d-5(0)-f-7(2)), green (tb3+, 542nm: d-5(4)-f-7(5)), or blue (ce3+, 450nm: 5d-4f) luminescence, respectively. pl, excitation, emission, and time-resolved spectra demonstrate that there is an energy transfer from ce3+ to tb3+ in the sio2@y2sio5:ce3+,tb3+ core/shell particles. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000241010300017 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/16277] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Lin CK,Wang H,Kong DY,et al. Silica supported submicron SiO2@Y2SiO5 : Eu3+ and SiO2@Y2SiO5 : Ce3+/Tb3+ spherical particles with a core-shell structure: Sol-gel synthesis and characterization[J]. european journal of inorganic chemistry,2006(18):3667-3675. |
APA | Lin CK.,Wang H.,Kong DY.,Yu M.,Liu XM.,...&Lin J.(2006).Silica supported submicron SiO2@Y2SiO5 : Eu3+ and SiO2@Y2SiO5 : Ce3+/Tb3+ spherical particles with a core-shell structure: Sol-gel synthesis and characterization.european journal of inorganic chemistry(18),3667-3675. |
MLA | Lin CK,et al."Silica supported submicron SiO2@Y2SiO5 : Eu3+ and SiO2@Y2SiO5 : Ce3+/Tb3+ spherical particles with a core-shell structure: Sol-gel synthesis and characterization".european journal of inorganic chemistry .18(2006):3667-3675. |
入库方式: OAI收割
来源:长春应用化学研究所
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