Nickel complexes catalyzed Heck reaction of iodobenzene and methyl acrylate
文献类型：期刊论文
| 作者 | Ma SY ; Wang HJ ; Gao KM ; Zhao FY |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2006 |
| 卷号 | 248期号:1-2页码:17-20 |
| 关键词 | HALIDES VINYLATION SOLVENTS ALKENES ARYL |
| ISSN号 | 1381-1169 |
| 通讯作者 | zhao fy |
| 中文摘要 | nickel appears the most promising for the replacement of palladium among the inexpensive transition metals for that it is active for heck reaction and about 500 times cheaper than palladium. in this article, we describe our recent results in the area of nickel-catalyzed heck vinylations. main focus is on the influence of ligand concentration in different organic solvents and the effects of the addition of water. the conversion is high in nmp and increases with increasing of pph3/ni ratio; in ethanol and toluene the conversion presents a maximum value on ni(pph3)(2). the effect of the addition of water is sensitive to the concentration of pph3 and the nature of solvent, it was well explained with the formation and transfer of the active species in the different solvent systems. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236916100003 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16339]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ma SY,Wang HJ,Gao KM,et al. Nickel complexes catalyzed Heck reaction of iodobenzene and methyl acrylate[J]. journal of molecular catalysis a-chemical,2006,248(1-2):17-20. |
| APA | Ma SY,Wang HJ,Gao KM,&Zhao FY.(2006).Nickel complexes catalyzed Heck reaction of iodobenzene and methyl acrylate.journal of molecular catalysis a-chemical,248(1-2),17-20. |
| MLA | Ma SY,et al."Nickel complexes catalyzed Heck reaction of iodobenzene and methyl acrylate".journal of molecular catalysis a-chemical 248.1-2(2006):17-20. |
入库方式： OAI收割
来源：长春应用化学研究所
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