Effect of different VOPO4 phase catalysts on oxidative dehydrogenation of cyclohexane to cyclohexene in acetic acid
文献类型：期刊论文
| 作者 | Zhu YJ ; Li J ; Xie XF ; Yang XG ; Wu Y |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2006 |
| 卷号 | 246期号:1-2页码:185-189 |
| 关键词 | VANADIUM PHOSPHORUS OXIDE SELECTIVE OXIDATION HYDROGEN-PEROXIDE MALEIC-ANHYDRIDE SUPPORTED VANADYL MILD OXIDATION ADIPIC ACID N-BUTANE ETHANE PHOSPHATE |
| ISSN号 | 1381-1169 |
| 通讯作者 | yang xg |
| 中文摘要 | alpha(1)-vopo4, alpha(ii)-vopo4 and beta-vopo4 have been investigated as catalysts for the gas phase oxidative dehydrogenation (odh) of cyclohexane to cyclohexene with the addition of acetic acid (hoac) in the feeds in a fixed bed reactor. different vopo4 phases showed different acidity and reducibility. beta-vopo4 phase is more active than alpha(i)-vopo4 and alpha(ii)-vopo4 in the odh without acetic acid addition. in the presence of acetic acid, the acidity of the catalyst may play an important role in the odh process. due to higher acidity, alpha(i)-vopo4 phase catalyst gives better catalytic performances than alpha(i)-vopo4 and beta-vopo4 for the odh of cyclohexane by adding of acetic acid in the reactants. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236061800027 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16341]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu YJ,Li J,Xie XF,et al. Effect of different VOPO4 phase catalysts on oxidative dehydrogenation of cyclohexane to cyclohexene in acetic acid[J]. journal of molecular catalysis a-chemical,2006,246(1-2):185-189. |
| APA | Zhu YJ,Li J,Xie XF,Yang XG,&Wu Y.(2006).Effect of different VOPO4 phase catalysts on oxidative dehydrogenation of cyclohexane to cyclohexene in acetic acid.journal of molecular catalysis a-chemical,246(1-2),185-189. |
| MLA | Zhu YJ,et al."Effect of different VOPO4 phase catalysts on oxidative dehydrogenation of cyclohexane to cyclohexene in acetic acid".journal of molecular catalysis a-chemical 246.1-2(2006):185-189. |
入库方式： OAI收割
来源：长春应用化学研究所
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