Sol-gel fabrication and photoluminescence properties of SiO2@Gd2O3 : Eu3+ core-shell particles
文献类型:期刊论文
作者 | Li GZ ; Yu M ; Wang ZL ; Lin J ; Wang RS ; Fang J |
刊名 | journal of nanoscience and nanotechnology
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出版日期 | 2006 |
卷号 | 6期号:5页码:1416-1422 |
关键词 | ER3+ PHOSPHOR FILMS COMBINATORIAL CHEMISTRY COLLOIDAL PARTICLES CHEMICAL-REACTIONS PHOTONIC CRYSTALS SOFT LITHOGRAPHY SPRAY-PYROLYSIS THIN-FILMS SILICA NANOPARTICLES |
ISSN号 | 1533-4880 |
通讯作者 | lin j |
中文摘要 | a uniform nanolayer of europium-doped gd2o3 was coated on the surface of preformed submicron silica spheres by a pechini sol-gel process. the resulted sio2@gd2o3:eu3+ core-shell structured phosphors were characterized by x-ray diffraction (xrd), fourier transform infrared spectroscopy (ft-ir), field emission scanning electron microscopy (fesem), transmission electron microscopy (tem), photoluminescence (pl) spectra as well as kinetic decays. the xrd results show that the gd2o3:eu3+ layers start to crystallize on the sio2 spheres after annealing at 400 degrees c and the crystallinity increases with raising the annealing temperature. the core-shell phosphors possess perfect spherical shape with narrow size distribution (average size: 640 nm) and non-agglomeration. the thickness of the gd2o3:eu3+ shells on the sio2 cores can be adjusted by changing the deposition cycles (70 nm for three deposition cycles). under short uv excitation, the obtained sio2@gd2o3:eu3+ particles show a strong red emission with d-5(0)-f-7(2) (610 nm) of eu3+ as the most prominent group.the pl intensity of eu3+ increases with increasing the annealing temperature and the number of coating cycles. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000238030200031 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/16413] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li GZ,Yu M,Wang ZL,et al. Sol-gel fabrication and photoluminescence properties of SiO2@Gd2O3 : Eu3+ core-shell particles[J]. journal of nanoscience and nanotechnology,2006,6(5):1416-1422. |
APA | Li GZ,Yu M,Wang ZL,Lin J,Wang RS,&Fang J.(2006).Sol-gel fabrication and photoluminescence properties of SiO2@Gd2O3 : Eu3+ core-shell particles.journal of nanoscience and nanotechnology,6(5),1416-1422. |
MLA | Li GZ,et al."Sol-gel fabrication and photoluminescence properties of SiO2@Gd2O3 : Eu3+ core-shell particles".journal of nanoscience and nanotechnology 6.5(2006):1416-1422. |
入库方式: OAI收割
来源:长春应用化学研究所
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