Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)
文献类型：期刊论文
| 作者 | Tao RJ ; Li FA ; Cheng YX ; Zang SQ ; Wang QL ; Niu JY ; Liao DZ |
| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2006 |
| 卷号 | 359期号:7页码:2053-2058 |
| 关键词 | TETRANUCLEAR COMPLEXES LIGANDS HEXAFLUOROACETYLACETONE INTERPENETRATION ARCHITECTURES MONONUCLEAR COPPER(II) ANISOTROPY OXIDATION MOLECULE |
| ISSN号 | 0020-1693 |
| 通讯作者 | tao rj |
| 中文摘要 | a chain coordination polymer with the chemical formula {[cu4l2(h2o)] (.) h2o)(n), has been synthesized by the assembly reaction of k(2)cul(.)1.5h(2)o and cu(oac)(2)(h2o)-h-. with a 1:1 mole ratio in methanol., where h4l=2-hydroxy-3-[(e)-({2-[(2-hydroxybenzoyl)imino]ethyl i imino)methyl] benzoic acid, oac(-) = ch3coo-. the crystal structure was determined by single-crystal x-ray diffraction analysis, the compound has chain molecular structure formed by dissymmetrical tetranuclear units. the magnetic measurements showed that cu-cu of the complex exhibit antiferromagnetic interactions, and satisfactory fittings to the observed magnetic susceptibility data were obtained by assuming a binuclear system, and further using molecular field approximation to deal with magnetic exchange interactions between binuclear systems. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236960800009 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16511]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tao RJ,Li FA,Cheng YX,et al. Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)[J]. inorganica chimica acta,2006,359(7):2053-2058. |
| APA | Tao RJ.,Li FA.,Cheng YX.,Zang SQ.,Wang QL.,...&Liao DZ.(2006).Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n).inorganica chimica acta,359(7),2053-2058. |
| MLA | Tao RJ,et al."Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)".inorganica chimica acta 359.7(2006):2053-2058. |
入库方式： OAI收割
来源：长春应用化学研究所
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