Synthesis, structure and ethylene polymerization of group 4 complexes with phosphinoamide ligands
文献类型：期刊论文
| 作者 | Qi CH ; Zhang SB ; Sun JH |
| 刊名 | applied organometallic chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 20期号:2页码:138-141 |
| 关键词 | OLEFIN POLYMERIZATION PHOSPHINIMIDE COMPLEXES LIVING POLYMERIZATION TITANIUM COMPLEXES DEACTIVATION PATHWAYS CATALYSTS ZIRCONIUM METALLOCENES REACTIVITY CONTAIN |
| ISSN号 | 0268-2605 |
| 通讯作者 | zhang sb |
| 中文摘要 | group 4 complexes containing diphosphinoamide ligands [ph2pnr](2)mcl2 (3: r = bu-t, m = ti; 4: r = bu-t, m = zr; 5: r = ph, m = ti; 6: r = ph, m = zr) were prepared by the reaction of mcl4 (m = ti; zr) with the corresponding lithium phosphinoamides in ether or thf. the structure of [(ph2pnbu)-bu-t](2)ticl2 (3) was determined by x-ray crystallography. the phosphinoamides functioned as eta(2)-coordination ligands in the solid state and the ti-n bond length suggests it is a simple single bond. in the presence of modified methylaluminoxane or i-bu3al/ph3bc(c6f5)(4), catalytic activity of up to 59.5 kg pe/mol cat h bar was observed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000234901600006 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16541]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qi CH,Zhang SB,Sun JH. Synthesis, structure and ethylene polymerization of group 4 complexes with phosphinoamide ligands[J]. applied organometallic chemistry,2006,20(2):138-141. |
| APA | Qi CH,Zhang SB,&Sun JH.(2006).Synthesis, structure and ethylene polymerization of group 4 complexes with phosphinoamide ligands.applied organometallic chemistry,20(2),138-141. |
| MLA | Qi CH,et al."Synthesis, structure and ethylene polymerization of group 4 complexes with phosphinoamide ligands".applied organometallic chemistry 20.2(2006):138-141. |
入库方式： OAI收割
来源：长春应用化学研究所
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