In situ electrochemical SERS studies on electrodeposition of aniline on 4-ATP/Au surface
文献类型：期刊论文
| 作者 | Jiao LS ; Wang ZJ ; Niu L ; Shen J ; You TY ; Dong SJ ; Ivaska A |
| 刊名 | journal of solid state electrochemistry
 |
| 出版日期 | 2006 |
| 卷号 | 10期号:11页码:886-893 |
| 关键词 | SELF-ASSEMBLED MONOLAYERS ENHANCED RAMAN-SCATTERING P-AMINOTHIOPHENOL MIXED MONOLAYERS POLYMER-FILMS POLYANILINE GOLD 4-AMINOTHIOPHENOL SPECTROSCOPY SILVER |
| ISSN号 | 1432-8488 |
| 通讯作者 | niu l |
| 中文摘要 | the electrochemical polymerization of 0.01 m aniline in 1 m h2so4 aqueous solution on roughened au surface modified with a self-assembled monolayer (sam) of 4-aminothiophenol (4-atp) has been investigated by in situ electrochemical surface-enhanced raman scattering spectroscopy (sers). the repeat units and possible structures of the electrodeposited polyaniline (pani) film were proposed; i.e., aniline monomer is coupled in head-to-tail predominately at the c-4 of aniline and amine of 4-atp, and the thin pani film is orientated vertically to substrate surface. simultaneous raman spectra during potential scanning indicate clearly that the ultrathin pani film (in initial growth of the film) consists of semiquinone radical cation (ip+), para-disubstituted benzene (ip and ip+) and quinine diimine (np) while it is oxidized, and without quinine diimine and semiquinone radical cation while reduced. meanwhile, the results confirm that 4-atp monolayer shows a strong promotion on the electrodeposition of aniline monomer, and a possible polymerization mechanism was proposed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000239720300002 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16673]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jiao LS,Wang ZJ,Niu L,et al. In situ electrochemical SERS studies on electrodeposition of aniline on 4-ATP/Au surface[J]. journal of solid state electrochemistry,2006,10(11):886-893. |
| APA | Jiao LS.,Wang ZJ.,Niu L.,Shen J.,You TY.,...&Ivaska A.(2006).In situ electrochemical SERS studies on electrodeposition of aniline on 4-ATP/Au surface.journal of solid state electrochemistry,10(11),886-893. |
| MLA | Jiao LS,et al."In situ electrochemical SERS studies on electrodeposition of aniline on 4-ATP/Au surface".journal of solid state electrochemistry 10.11(2006):886-893. |
入库方式： OAI收割
来源：长春应用化学研究所
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