Morphology and melt rheology of nylon 11/clay nanocomposites
文献类型：期刊论文
| 作者 | He XF ; Yang J ; Zhu LC ; Wang B ; Sun GP ; Lv PF ; Phang IY ; Liu TX |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2006 |
| 卷号 | 102期号:1页码:542-549 |
| 关键词 | LAYERED SILICATE NANOCOMPOSITES CONFINED POLYMER MELTS METHACRYLATE)/CLAY NANOCOMPOSITES EPSILON-CAPROLACTAM CLAY HYBRID CRYSTALLIZATION IRRADIATION KINETICS BEHAVIOR |
| ISSN号 | 0021-8995 |
| 通讯作者 | liu tx |
| 中文摘要 | nylon 11 (pa11)/clay nanocomposites have been prepared by melt-blending, followed by melt-extrusion through a capillary. transmission electron n-licroscopy shows that the exfoliated clay morphology is dominant for low nanofiller content, while the intercalated one is prevailing for high filler loading. melt rheological properties of pa11 nanocomposites have been studied in both linear and nonlinear viscoelastic response regions. in the linear regime, the nanocomposites exhibit much higher storage modulus (g') and loss modulus (g") values than neat pail the values of g' and g" increase steadily with clay loading at low concentrations, while the g' and g" for the sample with 5 wt % clay show an inverse dependence and lie between the modulus values of the samples with 1 and 2 wt % of clay. this is attributed to the alignment/orientation of nanoclay platelets in the intercalated nanocomposite induced by capillary extrusion. in the nonlinear regime, the nanocomposites show increased shear viscosities when compared with the neat resin. the dependence of the shear viscosity on clay loading has analogous trend to that of g' and g". |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000240045000069 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16721]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | He XF,Yang J,Zhu LC,et al. Morphology and melt rheology of nylon 11/clay nanocomposites[J]. journal of applied polymer science,2006,102(1):542-549. |
| APA | He XF.,Yang J.,Zhu LC.,Wang B.,Sun GP.,...&Liu TX.(2006).Morphology and melt rheology of nylon 11/clay nanocomposites.journal of applied polymer science,102(1),542-549. |
| MLA | He XF,et al."Morphology and melt rheology of nylon 11/clay nanocomposites".journal of applied polymer science 102.1(2006):542-549. |
入库方式： OAI收割
来源：长春应用化学研究所
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