Synthesis, characterization, crystal structure and magnetic property of asymmetrical double Schiff base heterotrinuclear complex: Cu(II)-Co(II)-Cu(II)
文献类型：期刊论文
| 作者 | Tao RJ ; Li FA ; Zang SQ ; Cheng YX ; Wang QL ; Niu JY ; Liao DZ |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 59期号:8页码:901-909 |
| 关键词 | DISSYMMETRICAL MONONUCLEAR ENTITIES NICKEL(II) COMPLEXES ORBITALS LIGANDS STATE |
| ISSN号 | 0095-8972 |
| 通讯作者 | tao rj |
| 中文摘要 | an asymmetrical double schiff-base cu(ii) mononuclear complex, hculp (h(3)lp is n-3-carboxylsalicylidene-n'-5-chlorosalicylaldehyde-1,3-diaminopropane) and a heterometal trinuclear complex with double molecular structure (culp)(2)co center dot 5h(2)o have been synthesized and characterized by means of elemental analyses, ir and electronic spectra. the crystal structure of the heterotrinucler complex was determined by x-ray analysis. each asymmetric unit within the unit cell of the complex contains two heterotrinuclear neutral molecules (a) [culpcoculp], (b) [(culph(2)o) coculp] and four uncoordinated water molecules. in the two neutral molecules, the central co2+ ions are located at the site of o-6 with a distorted octahedral geometry, one terminal cu2+ ion (cu(3)) at the square-pyramidal environment of n2o3, and the other three at the square planar coordination geometry with n2o2 donor atoms. magnetic properties of the heterotrinucler complex have been determined in the temperature range 5-300 k, indicating that the interaction between the central co2+ ion and the outer co2+ ions is antiferromagnetic. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000238247800008 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16757]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tao RJ,Li FA,Zang SQ,et al. Synthesis, characterization, crystal structure and magnetic property of asymmetrical double Schiff base heterotrinuclear complex: Cu(II)-Co(II)-Cu(II)[J]. journal of coordination chemistry,2006,59(8):901-909. |
| APA | Tao RJ.,Li FA.,Zang SQ.,Cheng YX.,Wang QL.,...&Liao DZ.(2006).Synthesis, characterization, crystal structure and magnetic property of asymmetrical double Schiff base heterotrinuclear complex: Cu(II)-Co(II)-Cu(II).journal of coordination chemistry,59(8),901-909. |
| MLA | Tao RJ,et al."Synthesis, characterization, crystal structure and magnetic property of asymmetrical double Schiff base heterotrinuclear complex: Cu(II)-Co(II)-Cu(II)".journal of coordination chemistry 59.8(2006):901-909. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。