Effects of acetic acid on product selectivity in gas phase oxidative dehydrogenation of cyclohexane
文献类型：期刊论文
| 作者 | Zhu YJ ; Li J ; Yang XG ; Wu Y |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2006 |
| 卷号 | 27期号:6页码:1118-1120 |
| 关键词 | GREEN ROUTE ADIPIC ACID CATALYSTS OXIDE |
| ISSN号 | 0251-0790 |
| 通讯作者 | yang xg |
| 中文摘要 | the effect of adding acetic acid on the product distribution in gas phase oxidative dehydrogenation of cyclohexane over alpha(1)-vopo4 catalyst was investigated. the role of acetic acid in the reaction process was put forward. the proposed mechanism is that acetic acid take precedence of cyclohexane adsorbing on the active sites of alpha(1)-vopo4 catalyst to form isolated active site. thus, cyclohexene species can desorb quickly from the active sites, avoiding its deep oxidation dehydrogenation. almost 100% selectivity to cyclohexene could be obtained when the molar ratio of acetic acid to cyclohexane was 12.9:1 at 450 degrees c, the conversion of cyclohexane was 6.9%. |
| 收录类别 | SCI |
| 语种 | 中文 |
| WOS记录号 | WOS:000238377500031 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16783]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu YJ,Li J,Yang XG,et al. Effects of acetic acid on product selectivity in gas phase oxidative dehydrogenation of cyclohexane[J]. chemical journal of chinese universities-chinese,2006,27(6):1118-1120. |
| APA | Zhu YJ,Li J,Yang XG,&Wu Y.(2006).Effects of acetic acid on product selectivity in gas phase oxidative dehydrogenation of cyclohexane.chemical journal of chinese universities-chinese,27(6),1118-1120. |
| MLA | Zhu YJ,et al."Effects of acetic acid on product selectivity in gas phase oxidative dehydrogenation of cyclohexane".chemical journal of chinese universities-chinese 27.6(2006):1118-1120. |
入库方式： OAI收割
来源：长春应用化学研究所
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