Investigation on isothermal and non-isothermal crystallization kinetics of poly (epsilon-caprolactone)
文献类型：期刊论文
| 作者 | Meng YF ; Wen HY ; Li HF ; Tang YJ ; Men YF ; Jiang SC ; An LJ |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2006 |
| 卷号 | 27期号:11页码:2198-2203 |
| 关键词 | SPHERULITIC CRYSTALLIZATION POLY(EPSILON-CAPROLACTONE) MORPHOLOGY BLENDS BEHAVIOR ETHER MELT PCL |
| ISSN号 | 0251-0790 |
| 通讯作者 | jiang sc |
| 中文摘要 | the crystallization kinetics and the development of lamellar structure during the isothermal crystallization of poly (epsilon-caprolactone) (pcl) were investigated by means of differential scanning calorimetry (dsc) and real-time synchrotron small angle x-ray scattering (sr-saxs) techniques, respectively. the avrami analysis was performed to obtain the kinetics parameters. the value of avrami index, n, is about 3, demonstrating a three-dimensional spherulitic growth on heterogeneous nuclei in the process of isothermal crystallization. the activation energy and the surface free energy of chain folding for isothermal crystallization were determined according to the arrhenius equation and hoffman-lauritzen theory, respectively. in the process of nonisothermal crystallization of pcl, the value of avrami index, n, is about 4, which demonstrates a three-dimensional spherulitic growth on homogeneous nuclei. in addition, lamellar parameters were obtained from the analysis of sr-saxs data. |
| 收录类别 | SCI |
| 语种 | 中文 |
| WOS记录号 | WOS:000242182500050 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/16797]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Meng YF,Wen HY,Li HF,et al. Investigation on isothermal and non-isothermal crystallization kinetics of poly (epsilon-caprolactone)[J]. chemical journal of chinese universities-chinese,2006,27(11):2198-2203. |
| APA | Meng YF.,Wen HY.,Li HF.,Tang YJ.,Men YF.,...&An LJ.(2006).Investigation on isothermal and non-isothermal crystallization kinetics of poly (epsilon-caprolactone).chemical journal of chinese universities-chinese,27(11),2198-2203. |
| MLA | Meng YF,et al."Investigation on isothermal and non-isothermal crystallization kinetics of poly (epsilon-caprolactone)".chemical journal of chinese universities-chinese 27.11(2006):2198-2203. |
入库方式： OAI收割
来源：长春应用化学研究所
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