Miscibility and crystallization behavior of poly(3-hydroxyvalerate-co-3-hydroxyvalerate)/poly(propylene carbonate) blends
文献类型:期刊论文
作者 | Peng SW ; An YX ; Chen C ; Fei B ; Zhuang YG ; Dong LS |
刊名 | journal of applied polymer science
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出版日期 | 2003 |
卷号 | 90期号:14页码:4054-4060 |
关键词 | POLY(-(D)-BETA-HYDROXYBUTYRIC ACID) THERMAL-DEGRADATION POLY(PROPYLENE CARBONATE) ALCALIGENES-EUTROPHUS MICROBIAL SYNTHESIS POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE) POLY(3-HYDROXYBUTYRATE-CO-4-HYDROXYBUTYRATE) DIOXIDE COPOLYMERIZATION STATE |
ISSN号 | 0021-8995 |
通讯作者 | dong ls |
中文摘要 | blends of synthetic poly(propylene carbonate) (ppc) with a natural bacterial copolymer of 3-hydroxybutyrate with 3-hydroxyvalerate (phbv) containing 8 mol % 3-hydroxyvalerate units were prepared with a simple casting procedure. ppc was thermally stabilized by end-capping before use. the miscibility, morphology, and crystallization behavior of the blends were investigated by differential scanning calorimetry, polarized optical microscopy, wide-angle x-ray diffraction (waxd), and small-angle xray scattering (saxs). phbv/ppc blends showed weak miscibility in the melt, but the miscibility was very low. the effect of ppc on the crystallization of phbv was evident. the addition of ppc decreased the rate of spherulite growth of phbv, and with increasing ppc content in the phbv/ppc blends, the phbv spherulites became more and more open. however, the crystalline structure of phbv did not change with increasing ppc in the phbv/ppc blends, as shown from waxd analysis. the long period obtained from saxs showed a small increase with the addition of ppc. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000186374700039 |
公开日期 | 2010-09-13 |
源URL | [http://202.98.16.49/handle/322003/17301] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Peng SW,An YX,Chen C,et al. Miscibility and crystallization behavior of poly(3-hydroxyvalerate-co-3-hydroxyvalerate)/poly(propylene carbonate) blends[J]. journal of applied polymer science,2003,90(14):4054-4060. |
APA | Peng SW,An YX,Chen C,Fei B,Zhuang YG,&Dong LS.(2003).Miscibility and crystallization behavior of poly(3-hydroxyvalerate-co-3-hydroxyvalerate)/poly(propylene carbonate) blends.journal of applied polymer science,90(14),4054-4060. |
MLA | Peng SW,et al."Miscibility and crystallization behavior of poly(3-hydroxyvalerate-co-3-hydroxyvalerate)/poly(propylene carbonate) blends".journal of applied polymer science 90.14(2003):4054-4060. |
入库方式: OAI收割
来源:长春应用化学研究所
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