Studies of electron-transfer and charge-transfer coupling processes at a liquid/liquid interface by double-barrel micropipet technique
文献类型：期刊论文
| 作者 | Chen Y ; Gao Z ; Li F ; Ge LH ; Zhang MQ ; Zhan DP ; Shao YH |
| 刊名 | analytical chemistry
 |
| 出版日期 | 2003 |
| 卷号 | 75期号:23页码:6593-6601 |
| 关键词 | LIQUID-LIQUID INTERFACE STANDARD GIBBS ENERGIES SCANNING ELECTROCHEMICAL MICROSCOPE FACILITATED ION TRANSFER CYCLIC VOLTAMMETRY POTENTIAL WINDOW WATER DIBENZO-18-CROWN-6 1 ITIES 2-DICHLOROETHANE |
| ISSN号 | 0003-2700 |
| 通讯作者 | shao yh |
| 中文摘要 | investigation of a heterogeneous electron-transfer (et) reaction at the water/1,2-dichloroethane interface employing a double-barrel micropipet technique is reported. the chosen system was the reaction between fe(cn)(6)(3-) in the aqueous phase (w) and ferrocene in 1,2-dichloroethane (dce). according to the generation and the collection currents as well as collection efficiency, the et-ion-transfer (it) coupling process at such an interface and competing reactions with the organic supporting electrolyte in the organic phase can be studied. in addition, this technique has been found to be an efficient method to distinguish and measure the charge-transfer coupling reaction between two ions (it-it) processes occurring simultaneously at a liquid/liquid interface. on this basis, the formal gibbs energies of transfer of some ions across the w/dce interface, such as no3-, no2-, cl-, coo-, tba(+), ipas+, cs+, rb+, k+, na+, and li+, for which their direct transfers are usually difficult to obtain because of the it-it coupling processes, were quantitatively evaluated. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000186986000035 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17365]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen Y,Gao Z,Li F,et al. Studies of electron-transfer and charge-transfer coupling processes at a liquid/liquid interface by double-barrel micropipet technique[J]. analytical chemistry,2003,75(23):6593-6601. |
| APA | Chen Y.,Gao Z.,Li F.,Ge LH.,Zhang MQ.,...&Shao YH.(2003).Studies of electron-transfer and charge-transfer coupling processes at a liquid/liquid interface by double-barrel micropipet technique.analytical chemistry,75(23),6593-6601. |
| MLA | Chen Y,et al."Studies of electron-transfer and charge-transfer coupling processes at a liquid/liquid interface by double-barrel micropipet technique".analytical chemistry 75.23(2003):6593-6601. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。