Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer
文献类型：期刊论文
| 作者 | Zang SQ ; Tao RJ ; Wang QL ; Hu NH ; Cheng YX ; Niu JY ; Liao DZ |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2003 |
| 卷号 | 42期号:3页码:761-766 |
| 关键词 | SOLVENT MOLECULES FULLY INTERLOCKED STRUCTURE BRIDGING TRANS-OXAMIDATE COPPER(II) COMPLEXES LINEAR-CHAIN LIGANDS NETWORK N ORTHO-PHENYLENEBIS(OXAMATO) FERROMAGNET N'-BIS(3-AMINOPROPYL)OXAMIDE |
| ISSN号 | 0020-1669 |
| 通讯作者 | tao rj |
| 中文摘要 | self-assembly of the building block [cu(oxbe)](-) with mn(ii) led to a novel coordination polymer {[cu(oxbe)]mn(h2o)(cu(oxbe)(dmf)]}(n).ndmf.nh(2)o, where h(3)oxbe is a new dissymmetrical ligand n-benzoato-n'-(2-aminoethyl)-oxamido and dmf = dimethylformamide. the crystal forms in the triclinic system, space group p(1)over-bar, with a = 9.260(4) angstorm, b = 12.833(5) angstrom, c = 15.274(6) angstrom , alpha = 76.18(3)degrees, beta = 82.7(3)degrees, gamma = 82.31(3)degrees, and z = 2. the crystal structure of the title complex reveals that the two-dimensional bimetallic layers are constructed of (cumnii)-mn-ii-cu-ii chains linked together by carboxylate bridge and hydrogen bonds help to produce a novel three-dimensional channel-like structure. the magnetic susceptibility measurements (5-300 k) were analyzed by means of the hamiltonian (h)over-cap = -2j(s)over-cap (mn)((s)over-cap(cu1) + (s)over-cap(cu2)), leading to j = -17.4 cm(-1). |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000180870300019 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17367]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zang SQ,Tao RJ,Wang QL,et al. Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer[J]. inorganic chemistry,2003,42(3):761-766. |
| APA | Zang SQ.,Tao RJ.,Wang QL.,Hu NH.,Cheng YX.,...&Liao DZ.(2003).Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer.inorganic chemistry,42(3),761-766. |
| MLA | Zang SQ,et al."Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer".inorganic chemistry 42.3(2003):761-766. |
入库方式： OAI收割
来源：长春应用化学研究所
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