Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6
文献类型：期刊论文
| 作者 | Chen Y ; Yuan Y ; Zhang MQ ; Li F ; Sun P ; Gao Z ; Shao YH |
| 刊名 | science in china series b-chemistry
 |
| 出版日期 | 2004 |
| 卷号 | 47期号:1页码:24-33 |
| 关键词 | LIQUID-LIQUID INTERFACE ASSISTED ION TRANSFER MACROCYCLIC POLYETHERS POTENTIAL WINDOW POTASSIUM-ION MICRO-ITIES SIDE-CHAINS WATER HYDROPHOBICITY MICROPIPETTES |
| ISSN号 | 1006-9291 |
| 通讯作者 | shao yh |
| 中文摘要 | facilitated ion transfer reactions of 20 amino acids with di.benzo-18-crown-6 (db18c6) at the water/1,2-dichloroethane (w/dce) interfaces supported at the tips of micro- and nano-pipets were investigated systematically using cyclic voltammetry. it was found that there were only 10 amino acids, that is, leu, val, ile, phe, trp, met, ala, gly, cys, gln (in brief), whose protonated forms as cations can give well-defined facilitated ion transfer voltammograms within the potential window, and the reaction pathway was proven to be consistent with the transfer by interfacial complexation/dissociation (tic/tid) mechanisms. the association constants of db 18c6 with different amino acids in the dce (beta(0)), and the kinetic parameters of reaction were evaluated based on the steady-state voltammetry of micro- or nano-pipets, respectively the experimental results demonstrated that the selectivity of complexation of protonated amino acid by db18c6 compared with that of alkali metal cations was low, which can be attributed to the vicinal effect arising from steric hindrance introduced by their side group and the steric bulk effect by lipophilic stabilization. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000188966900004 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/17369]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen Y,Yuan Y,Zhang MQ,et al. Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6[J]. science in china series b-chemistry,2004,47(1):24-33. |
| APA | Chen Y.,Yuan Y.,Zhang MQ.,Li F.,Sun P.,...&Shao YH.(2004).Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6.science in china series b-chemistry,47(1),24-33. |
| MLA | Chen Y,et al."Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6".science in china series b-chemistry 47.1(2004):24-33. |
入库方式： OAI收割
来源：长春应用化学研究所
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