Studies of effect of phase volume ratio on transfer of ionizable species across the water/1,2-dichloroethane interface by a three-electrode setup
文献类型：期刊论文
| 作者 | Zhang MQ ; Sun P ; Chen Y ; Li F ; Gao Z ; Shao YH |
| 刊名 | analytical chemistry
 |
| 出版日期 | 2003 |
| 卷号 | 75期号:16页码:4341-4345 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS IONIC PARTITION DIAGRAMS LIQUID-LIQUID INTERFACE WATER 1 LIQUID/LIQUID INTERFACES PHARMACOLOGICAL ACTIVITY GRAPHITE-ELECTRODES POTENTIAL WINDOW THIN-LAYERS VOLTAMMETRY 2-DICHLOROETHANE INTERFACE |
| ISSN号 | 0003-2700 |
| 通讯作者 | shao yh |
| 中文摘要 | the electrochemical behavior of pyridine distribution at the water/1,2-dichloroethane interface with variable phase volume ratios (r=v-0/v-w) was investigated by cyclic voltammetry. the system was composed of an aqueous droplet supported on a ag/agcl disk electrode covered with an organic solution or an organic droplet supported on a ag/agtpbcl disk electrode covered with an aqueous solution. in this way, a conventional three-electrode potentiostat can be used to study an ionizable compound transfer process at a liquid/liquid interface with a wide range of phase volume ratios (from 0.0004 to 1 and from 1 to 2500). using this special cell we designed, only very small volumes of both phase were needed for r equal to unity, which is very useful for the investigation of the distribution of ionizable species at a biphasic system when the available amount of species is limited. the ionic partition diagrams were obtained for different phase volume ratios. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000184798100053 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17377]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang MQ,Sun P,Chen Y,et al. Studies of effect of phase volume ratio on transfer of ionizable species across the water/1,2-dichloroethane interface by a three-electrode setup[J]. analytical chemistry,2003,75(16):4341-4345. |
| APA | Zhang MQ,Sun P,Chen Y,Li F,Gao Z,&Shao YH.(2003).Studies of effect of phase volume ratio on transfer of ionizable species across the water/1,2-dichloroethane interface by a three-electrode setup.analytical chemistry,75(16),4341-4345. |
| MLA | Zhang MQ,et al."Studies of effect of phase volume ratio on transfer of ionizable species across the water/1,2-dichloroethane interface by a three-electrode setup".analytical chemistry 75.16(2003):4341-4345. |
入库方式： OAI收割
来源：长春应用化学研究所
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