Electrochemical study of PW12O403- in poly(ethylene glycol) electrolyte
文献类型：期刊论文
| 作者 | Zhao F ; Gu NY ; Liu SQ ; Wang ZX ; Dong SJ |
| 刊名 | electroanalysis
 |
| 出版日期 | 2003 |
| 卷号 | 15期号:8页码:695-701 |
| 关键词 | SOLID-STATE VOLTAMMETRY POLYMERIC ELECTROLYTES FILMS FERROCENE BEHAVIOR LIQUIDS |
| ISSN号 | 1040-0397 |
| 通讯作者 | dong sj |
| 中文摘要 | the electrochemical properties of pw12o403- (abbreviated as pw12) anion in poly(ethylene glycol) (peg) have been studied by cyclic voltammetry, complex impedance and ft-ir spectroscopy. the pw12 anion in peg-liclo4 electrolyte shows reasonable facile electrochemistry, and the diffusion coefficients of pw12 were measured with microelectrode. it is shown that ionic conductivity of polymer electrolytes based on low molecular weight peg can be improved by the addition of pw12. the increase of conductivity is coupled with decrease of transient cross-links density of polymer chains which is evidenced by the downshift of c-o-c stretching mode. the phenomena are explained in view of ion-ion and ion-polymer interactions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000183503700004 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17407]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao F,Gu NY,Liu SQ,et al. Electrochemical study of PW12O403- in poly(ethylene glycol) electrolyte[J]. electroanalysis,2003,15(8):695-701. |
| APA | Zhao F,Gu NY,Liu SQ,Wang ZX,&Dong SJ.(2003).Electrochemical study of PW12O403- in poly(ethylene glycol) electrolyte.electroanalysis,15(8),695-701. |
| MLA | Zhao F,et al."Electrochemical study of PW12O403- in poly(ethylene glycol) electrolyte".electroanalysis 15.8(2003):695-701. |
入库方式： OAI收割
来源：长春应用化学研究所
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