From dissymmetrical mononuclear entities to centrosymmetrical heterotrinuclear complex with 2D supramolecular structure: synthesis, characterization, crystal structure, and magnetic properties
文献类型：期刊论文
| 作者 | Tao RJ ; Zang SQ ; Hu NH ; Wang QL ; Cheng YX ; Niu JY ; Liao DZ |
| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2003 |
| 卷号 | 353页码:325-331 |
| 关键词 | HYDROGEN-BONDED NETWORK II/GD-III COUPLE M = CR COORDINATION POLYMERS 3-DIMENSIONAL NETWORKS FERRIMAGNETIC CHAINS COPPER(II) COMPLEXES INTRINSIC PROPERTY SOLID-STATE LIGANDS |
| ISSN号 | 0020-1693 |
| 通讯作者 | tao rj |
| 中文摘要 | a new centrosymmetrical heterotrinuclear complex, {[cu(oxbe)](2)co(h2o)(2)}.2dmf.dma with 2d supramolecular structure, has been obtained by the self-assembly of a dissymmetrical building block [cu(oxbe)](-) with bivalent metal ion co2+, where h(3)oxbe is dissymmetrical ligand n-benzoato-n'-(2-aminoethyl)oxamido, dmf = dimethylformamide, dma = dimethylamine. its structure was determined by single crystal x-ray analysis. the molecular structure is centrosymmetrical with the cobalt atom lying on an inversion center. through the hydrogen bonds and d-pi stacking interactions, a 2d supramolecular structure is formed. this study exemplifies a new method for the assembly of supramolecular structure using a dissymmetrical brick. magnetic susceptibility measurements (5-300 k) indicate that the central cobalt and terminal copper metal ions are antiferromagnetically coupled with j = -23.1 cm(-1). |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000185519900044 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17579]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tao RJ,Zang SQ,Hu NH,et al. From dissymmetrical mononuclear entities to centrosymmetrical heterotrinuclear complex with 2D supramolecular structure: synthesis, characterization, crystal structure, and magnetic properties[J]. inorganica chimica acta,2003,353:325-331. |
| APA | Tao RJ.,Zang SQ.,Hu NH.,Wang QL.,Cheng YX.,...&Liao DZ.(2003).From dissymmetrical mononuclear entities to centrosymmetrical heterotrinuclear complex with 2D supramolecular structure: synthesis, characterization, crystal structure, and magnetic properties.inorganica chimica acta,353,325-331. |
| MLA | Tao RJ,et al."From dissymmetrical mononuclear entities to centrosymmetrical heterotrinuclear complex with 2D supramolecular structure: synthesis, characterization, crystal structure, and magnetic properties".inorganica chimica acta 353(2003):325-331. |
入库方式： OAI收割
来源：长春应用化学研究所
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