A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na-2[{Mn(phen)(2)(H2O)}{Mn(phen)(2)}(3){Mn (Mo12O24)-O-V (HPO4)(6)(PO4)(2)(OH)(6)}] center dot 4H(2)O (phen=1,10-phenanthroline)
文献类型：期刊论文
| 作者 | Yuan M ; Wang EB ; Lu Y ; Li YG ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2003 |
| 卷号 | 170期号:1页码:192-197 |
| 关键词 | ORGANIC/INORGANIC HYBRID MATERIALS M = CO CRYSTAL-STRUCTURE CLUSTERS MOLYBDOPHOSPHATE OCTAMOLYBDATE NI |
| ISSN号 | 0022-4596 |
| 通讯作者 | wang eb |
| 中文摘要 | an organic-inorganic hybrid molybdenum phosphate, na-2[{mn(phen)(2)(h2o)} {mn(phen)(2)}(3){(mnmo12o24)-o-v (hpo4)(6)(po4)(2) (oh)(6)}] . 4h(2)o (phen=1,10-phenanthroline), involving molybdenum present in v oxidation state and covalently bonded transition metal coordination complexes, has been hydrothermally synthesized and structurally characterized by single-crystal x-ray diffraction. deep brown-red crystals are formed in the triclinic system, space group p (1) over bar, a=16.581(l)angstrom, b=18.354(1)angstrom, c=24.485(2)angstrom, alpha=80.589(l)degrees, beta=71.279(1)degrees, gamma=67.084(1)degrees, v=6493.8(8)angstrom(3), z=2, lambda(mokalpha)=0.71073angstrom (r(f)=0.0686 for 29,053 reflections). data were collected on a bruker smart apex ccd diffractometer at 293 k in the range of 1.76 < theta < 28.06degrees using omega-2theta scans technique. the structure of the title compound may be considered to be based on {mo6o12(hpo4)(3)(po4)(oh)(3)} units bonded together with {mn(phen)(2)} subunits into a two-dimensional network. two types of tunnels are observed in the solid of the title compound. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000181875000023 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17583]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan M,Wang EB,Lu Y,et al. A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na-2[{Mn(phen)(2)(H2O)}{Mn(phen)(2)}(3){Mn (Mo12O24)-O-V (HPO4)(6)(PO4)(2)(OH)(6)}] center dot 4H(2)O (phen=1,10-phenanthroline)[J]. journal of solid state chemistry,2003,170(1):192-197. |
| APA | Yuan M.,Wang EB.,Lu Y.,Li YG.,Hu CW.,...&Jia HQ.(2003).A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na-2[{Mn(phen)(2)(H2O)}{Mn(phen)(2)}(3){Mn (Mo12O24)-O-V (HPO4)(6)(PO4)(2)(OH)(6)}] center dot 4H(2)O (phen=1,10-phenanthroline).journal of solid state chemistry,170(1),192-197. |
| MLA | Yuan M,et al."A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na-2[{Mn(phen)(2)(H2O)}{Mn(phen)(2)}(3){Mn (Mo12O24)-O-V (HPO4)(6)(PO4)(2)(OH)(6)}] center dot 4H(2)O (phen=1,10-phenanthroline)".journal of solid state chemistry 170.1(2003):192-197. |
入库方式： OAI收割
来源：长春应用化学研究所
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