The synthesis and crystal structure of vanadium complexes: [(VO2)-O-IV(phen)(2)]center dot 6H(2)O and [2,2 '-(bipy)(2)(VO2)-O-V](H2BO3)center dot 3H(2)O
文献类型：期刊论文
| 作者 | Qi YJ ; Yang YL ; Cao MH ; Hu CW ; Wang EB ; Hu NH ; Jia HQ |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2003 |
| 卷号 | 648期号:3页码:191-201 |
| 关键词 | HYDROTHERMAL SYNTHESIS MOLECULAR MANIPULATION OXIDE SOLIDS |
| ISSN号 | 0022-2860 |
| 通讯作者 | hu cw |
| 中文摘要 | the organic-inorganic hybrid materials vanadium oxide [(vo2)-o-iv(phen)(2)](.)6h(2)o (1) and [(2,2'-bipy)(2)(vo2)-o-v](h2bo3)(.)3h(2)o (2) have been conventional and hydrothermal synthesized and characterized by single crystal x-ray diffraction, elemental analyses, respectively. although the method and the ligand had been used in the syntheses of the compounds (1) and (2) are different, they almost possess similar structure. they all exhibit the distorted octahedral [vo2n4] unit with organonitrogen donors of the phen and 2,2'-bipy ligands, respectively, which coordinated directly to the vanadium oxide framework. and they are both non-mixed-valence complexes. but the compound (1) is isolated, and the compound (2) consists of a cation of [(2,2'-bipy)(2)(vo2)-o-v](+) and an anion of (h2bo3)(-). so the valence of vanadium of (1) and (2) are tetravalence and pentavalence, respectively. meanwhile it is noteworthy that pi-pi stacking interaction between adjacent phen and 2,2'-bipy groups in compounds i and 2 also play a significant role in stabilization of the structure. thus, the structure of [(vo2)-o-iv(phen)(2)](.)6h(2)o and [(2,2'-bipy)(2)(vo2)-o-v](h2bo3)(.)3h(2)o are both further extended into interesting three-dimensional supramolecular. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000181533900005 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17585]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qi YJ,Yang YL,Cao MH,et al. The synthesis and crystal structure of vanadium complexes: [(VO2)-O-IV(phen)(2)]center dot 6H(2)O and [2,2 '-(bipy)(2)(VO2)-O-V](H2BO3)center dot 3H(2)O[J]. journal of molecular structure,2003,648(3):191-201. |
| APA | Qi YJ.,Yang YL.,Cao MH.,Hu CW.,Wang EB.,...&Jia HQ.(2003).The synthesis and crystal structure of vanadium complexes: [(VO2)-O-IV(phen)(2)]center dot 6H(2)O and [2,2 '-(bipy)(2)(VO2)-O-V](H2BO3)center dot 3H(2)O.journal of molecular structure,648(3),191-201. |
| MLA | Qi YJ,et al."The synthesis and crystal structure of vanadium complexes: [(VO2)-O-IV(phen)(2)]center dot 6H(2)O and [2,2 '-(bipy)(2)(VO2)-O-V](H2BO3)center dot 3H(2)O".journal of molecular structure 648.3(2003):191-201. |
入库方式： OAI收割
来源：长春应用化学研究所
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