In situ ethylene homopolymerization and copolymerization catalyzed by zirconocene catalysts entrapped inside functionalized montmorillonite
文献类型：期刊论文
| 作者 | Liu CB ; Tang T ; Wang D ; Huang BT |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2003 |
| 卷号 | 41期号:14页码:2187-2196 |
| 关键词 | POLYMERIZATION CATALYSTS OLEFIN POLYMERIZATION TITANIUM CATALYSTS COMPLEXES NANOCOMPOSITES INTERCALATION METALLOCENES SILICATES ETHENE |
| ISSN号 | 0887-624x |
| 通讯作者 | tang t |
| 中文摘要 | ethylene homopolymerizations and copolymerizations were catalyzed by zirconocene catalysts entrapped inside functionalized. montmorillonites that had been rendered organophilic via the ion exchange of the interlamellar cations of layered montmorillonite with hydrochlorides of l-amino acids (aah(+)cl(-)) or their methyl esters (meaah(+)cl(-)), with or without the further addition of hexadecyltrimethylammonium bromide (c16h33n+me3br-; r4n+br-). in contrast to the homogeneous cp2zrcl2/methylaluminoxane catalyst for ethylene homopolymerizations and copolymerizations with 1-octene, the intercalated cp2zrcl2 activated by methylaluminoxane for ethylene homopolymerizations and copolymerizations with 1-octene proved to be more effective in the synthesis of polyethylenes with controlled molecular weights, chemical compositions and structures, and properties, including the bulk density. the effects of the properties of the organic guests on the preparation and catalytic performance of the intercalated zirconocene catalysts were studied. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000183812100006 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17625]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu CB,Tang T,Wang D,et al. In situ ethylene homopolymerization and copolymerization catalyzed by zirconocene catalysts entrapped inside functionalized montmorillonite[J]. journal of polymer science part a-polymer chemistry,2003,41(14):2187-2196. |
| APA | Liu CB,Tang T,Wang D,&Huang BT.(2003).In situ ethylene homopolymerization and copolymerization catalyzed by zirconocene catalysts entrapped inside functionalized montmorillonite.journal of polymer science part a-polymer chemistry,41(14),2187-2196. |
| MLA | Liu CB,et al."In situ ethylene homopolymerization and copolymerization catalyzed by zirconocene catalysts entrapped inside functionalized montmorillonite".journal of polymer science part a-polymer chemistry 41.14(2003):2187-2196. |
入库方式： OAI收割
来源：长春应用化学研究所
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