Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis(chlorophthalimide)s
文献类型：期刊论文
| 作者 | Gao CL ; Zhang SB ; Gao LX ; Ding MX |
| 刊名 | macromolecules
 |
| 出版日期 | 2003 |
| 卷号 | 36期号:15页码:5559-5565 |
| 关键词 | SOLUBLE POLY(PARA-PHENYLENE)S BIS(ETHER ANHYDRIDE)S AROMATIC DICHLORIDES POLY(ETHER IMIDE)S CARBON-MONOXIDE DIANHYDRIDE POLYCONDENSATION DIBROMIDES DIAMINES |
| ISSN号 | 0024-9297 |
| 通讯作者 | zhang sb |
| 中文摘要 | a facile method for the synthesis of biphenyl polyimides, which involves the nickel-catalyzed coupling of aromatic dichlorides containing imide structure in the presence of zinc and triphenylphosphine, has been developed. the polymerizations proceeded smoothly under mild conditions and produced biphenyl polyimides with inherent viscosities of 0.13-0.98 dl/g. the polymerizations of bis(4-chlorophthalimide)s with bulky side substituents gave high molecular weight polymers. low molecular weight polymers from bis(4-chlorophthalimide)s containing rigid diamine moieties and bis(3-chlorophthalimide)s were obtained because of the formations of polymer precipitate and cyclic oligoimides, respectively. the effects of various factors, such as amount of catalyst, solvent volume, ligand, reaction temperature, and time, on the polymerization were studied. the random copolymerization of two bis(chlorophthalimide)s in varying proportions produced medium molecular weight material. the tgs of prepared polyimides were observed at 245-311 degreesc, and the thermogravimetry of polymers showed 10% weight loss in nitrogen at 470-530 degreesc. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000184398600019 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17757]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao CL,Zhang SB,Gao LX,et al. Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis(chlorophthalimide)s[J]. macromolecules,2003,36(15):5559-5565. |
| APA | Gao CL,Zhang SB,Gao LX,&Ding MX.(2003).Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis(chlorophthalimide)s.macromolecules,36(15),5559-5565. |
| MLA | Gao CL,et al."Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis(chlorophthalimide)s".macromolecules 36.15(2003):5559-5565. |
入库方式： OAI收割
来源：长春应用化学研究所
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