Hydrothermal syntheses and crystal structures of new cage-like mixed-valent polyoxovanadates
文献类型：期刊论文
| 作者 | Li YG ; Lu Y ; Luan GY ; Wang EB ; Duan YB ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | polyhedron
 |
| 出版日期 | 2002 |
| 卷号 | 21期号:25-26页码:2601-2608 |
| 关键词 | MOLYBDENUM PHOSPHATE VANADIUM-OXIDE BATTERIES CLUSTERS TUNNEL |
| ISSN号 | 0277-5387 |
| 通讯作者 | wang eb |
| 中文摘要 | three new cage-like mixed-valent polyoxovanadates [ni(1,10'-phen)(3)](2)[v10o26] 1, [zn(2,2'-bipy)(3)](3)[v15o36cl](.)3h(2)o (2) and [co(2,2'-bipy)(3)](3)[v15o36cl](.)3h(2)o (3) have been hydrothermally synthesized for the first time and characterized by elemental analyses, ir, epr spectra, tg analyses and single crystal x-ray diffraction. the polyoxoanion of i exhibits an interesting empty ellipsoidal [v-2(iv) v-8(v) o-26](4-) 'host' shell, while the oxo vanadium clusters of 2 and 3 possess a spherical [v-8(iv) v-7(v) o36cl](6-) cage with a cl- ion encapsulated. the structure-directing role of organic templates (1,10'-phen and 2,2'-bipy) on the formation of the polyoxoanion structures is discussed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000179569000010 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17839]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li YG,Lu Y,Luan GY,et al. Hydrothermal syntheses and crystal structures of new cage-like mixed-valent polyoxovanadates[J]. polyhedron,2002,21(25-26):2601-2608. |
| APA | Li YG.,Lu Y.,Luan GY.,Wang EB.,Duan YB.,...&Jia HQ.(2002).Hydrothermal syntheses and crystal structures of new cage-like mixed-valent polyoxovanadates.polyhedron,21(25-26),2601-2608. |
| MLA | Li YG,et al."Hydrothermal syntheses and crystal structures of new cage-like mixed-valent polyoxovanadates".polyhedron 21.25-26(2002):2601-2608. |
入库方式： OAI收割
来源：长春应用化学研究所
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