Copolymerization of carbon dioxide and propylene oxide with neodymium trichloroacetate-based coordination catalyst
文献类型:期刊论文
作者 | Liu BY ; Zhao XJ ; Wang XH ; Wang FS |
刊名 | polymer
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出版日期 | 2003 |
卷号 | 44期号:6页码:1803-1808 |
关键词 | EPICHLOROHYDRIN FIXATION SYSTEMS CO2 |
ISSN号 | 0032-3861 |
通讯作者 | wang xh |
中文摘要 | the copolymerizations of carbon dioxide (co2) and propylene oxide (po) were performed using new ternary rare-earth catalyst, it was found that the rare-earth coordination catalyst consisting of nd(ccl3coo)(3), znet2 and glycerine was very effective for the copolymerization of po with co2. the effects of the relative molar ratio and addition order of the catalyst components, copolymerization reaction time, and operating pressure as well as temperature on the copolymerization were systematically investigated. at an appropriate combination of all variables, the yield could be as high as 6875 g/mol nd per hour at 90 degreesc in a 8 h reaction period. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000181260900004 |
公开日期 | 2010-09-13 |
源URL | [http://202.98.16.49/handle/322003/17865] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu BY,Zhao XJ,Wang XH,et al. Copolymerization of carbon dioxide and propylene oxide with neodymium trichloroacetate-based coordination catalyst[J]. polymer,2003,44(6):1803-1808. |
APA | Liu BY,Zhao XJ,Wang XH,&Wang FS.(2003).Copolymerization of carbon dioxide and propylene oxide with neodymium trichloroacetate-based coordination catalyst.polymer,44(6),1803-1808. |
MLA | Liu BY,et al."Copolymerization of carbon dioxide and propylene oxide with neodymium trichloroacetate-based coordination catalyst".polymer 44.6(2003):1803-1808. |
入库方式: OAI收割
来源:长春应用化学研究所
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