Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst
文献类型：期刊论文
| 作者 | Rong GZ ; Deng MX ; Deng C ; Tang ZH ; Piao LH ; Chen XS ; Jing XB |
| 刊名 | biomacromolecules
 |
| 出版日期 | 2003 |
| 卷号 | 4期号:6页码:1800-1804 |
| 关键词 | RING-OPENING POLYMERIZATION BIODEGRADABLE POLYMERS TRIBLOCK COPOLYMERS DIBLOCK OLIGOMERS POLYPEPTIDES PEPTIDE SURGERY |
| ISSN号 | 1525-7797 |
| 通讯作者 | chen xs |
| 中文摘要 | a biodegradable two block copolymer, poly(epsilon-caprolactone)-b- poly(gamma-benzyl-l-glutamic acid) (pcl-pblg) was synthesized successfully by ring-opening polymerization of n-carboxyanhydride of gamma-benzyl-l-glutamate (blg-nca) with aminophenyl-terminated pcl as a macroinitiator. the aminophenethoxyl-terminated pcl was prepared via hydrogenation of a 4-nitrophenethoxyl-teminated pcl, which was novelly obtained from the polymerization of c-caprolactone (cl) initiated by amino calcium 4-nitrobenzoxide. the structures of the block copolymer and its precursors from the initial step of pcl were confirmed and investigated by h-1 nmr, ft-ir, gpc, and ft-icrms analyses and dsc measurements. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000186729700044 |
| 公开日期 | 2010-09-13 |
| 源URL | [http://202.98.16.49/handle/322003/17925]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Rong GZ,Deng MX,Deng C,et al. Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst[J]. biomacromolecules,2003,4(6):1800-1804. |
| APA | Rong GZ.,Deng MX.,Deng C.,Tang ZH.,Piao LH.,...&Jing XB.(2003).Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst.biomacromolecules,4(6),1800-1804. |
| MLA | Rong GZ,et al."Synthesis of poly(epsilon-caprolactone)-b-poly(gamma-benzyl-L-glutamic acid) block copolymer using amino organic calcium catalyst".biomacromolecules 4.6(2003):1800-1804. |
入库方式： OAI收割
来源：长春应用化学研究所
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