中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Surface-enhanced Raman spectroscopy of microperoxidase-11 on roughed silver electrodes

文献类型:期刊论文

作者Wang FB ; Zheng JW ; Li XW ; Ji YA ; Gao Y ; Xing W ; Lu TH
刊名journal of electroanalytical chemistry
出版日期2003
卷号545页码:123-128
关键词HEME OCTAPEPTIDE MICROPEROXIDASE-8 RESONANCE RAMAN CYTOCHROME-C HYDROGEN-PEROXIDE REDUCTION SPECTRA HEMOPROTEINS SCATTERING PROTEINS PORPHYRINS
ISSN号0022-0728
通讯作者zheng jw
中文摘要the conformation of microperoxidase-11 (mp-11) adsorbed on roughened silver electrodes was studied using surface-enhanced fourier transform raman spectroscopy. the results demonstrate that mp-11 was initially adsorbed via its polypeptide chain with a alpha-helix conformation, as indicated by the enhancement of the characteristic bands related to the amides i and iii. the weak resonance effect of the porphyrin macrocycle in the near ir region contributes to the spectrum of the heme group. the presence of imidazole as the sixth ligand to the heme iron influences the conformation of the polypeptide chain of mp-11 on the electrode surface. evaporation of solvent water results in an opened conformation of the adsorbed mp-11. which allows the heme group to contact the electrode surface directly.
收录类别SCI
语种英语
WOS记录号WOS:000182177900016
公开日期2010-09-13
源URL[http://202.98.16.49/handle/322003/18009]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wang FB,Zheng JW,Li XW,et al. Surface-enhanced Raman spectroscopy of microperoxidase-11 on roughed silver electrodes[J]. journal of electroanalytical chemistry,2003,545:123-128.
APA Wang FB.,Zheng JW.,Li XW.,Ji YA.,Gao Y.,...&Lu TH.(2003).Surface-enhanced Raman spectroscopy of microperoxidase-11 on roughed silver electrodes.journal of electroanalytical chemistry,545,123-128.
MLA Wang FB,et al."Surface-enhanced Raman spectroscopy of microperoxidase-11 on roughed silver electrodes".journal of electroanalytical chemistry 545(2003):123-128.

入库方式: OAI收割

来源:长春应用化学研究所

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