Effect of alkyl group length on the conductivity in the 2,3,7,8,12,13,17,18-octakis(alkyl-thio)tetraazaporphyrins and redox properties of the metallooctakis(hexyl-thio)tetraazaporphyrins
文献类型：期刊论文
| 作者 | Yu B ; Zhou YX ; Wang DK ; Wang ZX ; Sugiura K ; Sakata Y ; Levon K |
| 刊名 | journal of porphyrins and phthalocyanines
 |
| 出版日期 | 2002 |
| 卷号 | 6期号:7-8页码:447-455 |
| 关键词 | LANGMUIR-BLODGETT-FILMS DISCOTIC MESOMORPHISM COMPLEX PORPHYRAZINES DERIVATIVES MONOLAYERS BEHAVIOR |
| ISSN号 | 1088-4246 |
| 通讯作者 | zhou yx |
| 中文摘要 | a series of 2,3,7,8,12,13,17,18-octakis(alkyl-thio)tetraazaporphyrins (h(2)oattap) with different alkyl chain lengths have been synthesized. cyclic voltammetry and differential pulse voltammetry have been used to investigate the effect of the controlled lengths of the eight peripheral thioether tails on the redox behavior of the molecules. the electrochemical reduction of octakis(hexyl-thio)tetraazaporphyrins, mohttap (where m = cu, ni), was studied in 1,2-dichloroethane at a platinum electrode. the cu derivative was oxidized in one single-electron-transfer step to yield a pi-cation radical and reduced in three single-electron-transfer steps to yield a pi-anion radical, dianion and trianion, respectively. for the ni derivative, electron transfer reactions involving both the central metal atom and the macrocyclic ring were observed. electron transfer pathways are proposed based upon voltammetric and in situ spectroelectrochemical results. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000181250000001 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18121]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yu B,Zhou YX,Wang DK,et al. Effect of alkyl group length on the conductivity in the 2,3,7,8,12,13,17,18-octakis(alkyl-thio)tetraazaporphyrins and redox properties of the metallooctakis(hexyl-thio)tetraazaporphyrins[J]. journal of porphyrins and phthalocyanines,2002,6(7-8):447-455. |
| APA | Yu B.,Zhou YX.,Wang DK.,Wang ZX.,Sugiura K.,...&Levon K.(2002).Effect of alkyl group length on the conductivity in the 2,3,7,8,12,13,17,18-octakis(alkyl-thio)tetraazaporphyrins and redox properties of the metallooctakis(hexyl-thio)tetraazaporphyrins.journal of porphyrins and phthalocyanines,6(7-8),447-455. |
| MLA | Yu B,et al."Effect of alkyl group length on the conductivity in the 2,3,7,8,12,13,17,18-octakis(alkyl-thio)tetraazaporphyrins and redox properties of the metallooctakis(hexyl-thio)tetraazaporphyrins".journal of porphyrins and phthalocyanines 6.7-8(2002):447-455. |
入库方式： OAI收割
来源：长春应用化学研究所
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