Charge transfer across the water/nitrobenzene interface by three-electrode system
文献类型：期刊论文
| 作者 | Yuan Y ; Gao Z ; Zhang MQ ; Zhang ZQ ; Shao YH |
| 刊名 | science in china series b-chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 45期号:5页码:494-502 |
| 关键词 | ION TRANSFER-REACTIONS LIQUID INTERFACE LIQUID/LIQUID INTERFACES NITROBENZENE VOLTAMMETRY WATER |
| ISSN号 | 1006-9291 |
| 通讯作者 | yuan y |
| 中文摘要 | a droplet of aqueous solution containing a certain molar ratio of redox couple is first attached onto a platinum electrode surface, then the resulting drop electrode is immersed into the organic solution containing very hydrophobic electrolyte. combined with reference and counter electrodes, a classical three-electrode system has been constructed, ion transfer (it) and electron transfer (et) are investigated systematically using three-electrode voltammetry. potassium ion transfer and electron transfer between potassium ferricyanide in the aqueous phase and ferrocene in nitrobenzene are observed with potassium ferricyanide/potassium ferrocyanide as the redox couple. meanwhile, the transfer reactions of lithium, sodium, potassium, proton and ammonium ions are obtained with ferric sulfate/ferrous sulfate as the redox couple. the formal transfer potentials and the standard gibbs transfer energy of these ions are evaluated and consistent with the results obtained by a four-electrode system and other methods. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000178162500008 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18315]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan Y,Gao Z,Zhang MQ,et al. Charge transfer across the water/nitrobenzene interface by three-electrode system[J]. science in china series b-chemistry,2002,45(5):494-502. |
| APA | Yuan Y,Gao Z,Zhang MQ,Zhang ZQ,&Shao YH.(2002).Charge transfer across the water/nitrobenzene interface by three-electrode system.science in china series b-chemistry,45(5),494-502. |
| MLA | Yuan Y,et al."Charge transfer across the water/nitrobenzene interface by three-electrode system".science in china series b-chemistry 45.5(2002):494-502. |
入库方式： OAI收割
来源：长春应用化学研究所
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