An unusual organic-inorganic chain-like hybrid complex [(CuCl)(2)(o-phen)](infinity) (o-phen=o-phenanthroline)
文献类型：期刊论文
| 作者 | Wang ST ; Li YG ; Wang EB ; Luan GY ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 167期号:2页码:402-406 |
| 关键词 | X = CL CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS SYSTEM BR |
| ISSN号 | 0022-4596 |
| 通讯作者 | wang eb |
| 中文摘要 | a novel organic-inorganic hybrid complex [(cucl)(2) (o-phen)](infinity) 1 (o-phen = o-phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analyses, xps spectrum, tg analysis, and single-crystal x-ray diffraction. compound i crystallizes in the monoclinic system, space group p2(1)/n, a = 3.7285(7) angstrom, b = 19.603(4) angstrom, c = 16.757(3) angstrom, beta = 95.83(3)degrees, v = 1218.4(4) angstrom(3), z = 4, lambda(mokalpha) = 0.71073 angstrom (r(f) = 0.0643 for 2559 reflections). data were collected on an r-axis rapid diffractometer at 293 k in the range of 1.60 < θ < 27.48degrees. the title compound exhibits a one-dimensional chain-like scaffolding constructed by the unusual [cu3cl3] hexagon motifs by, sharing opposite edges. only cu(1) sites of the [cu3cl3] hexagon are coordinated with n donors of o-phen groups. furthermore, the three-dimensional supermolecular architecture is formed by c-h...cl hydrogen bonds between o-phen groups and cucl chains. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000178108700019 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18319]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang ST,Li YG,Wang EB,et al. An unusual organic-inorganic chain-like hybrid complex [(CuCl)(2)(o-phen)](infinity) (o-phen=o-phenanthroline)[J]. journal of solid state chemistry,2002,167(2):402-406. |
| APA | Wang ST.,Li YG.,Wang EB.,Luan GY.,Hu CW.,...&Jia HQ.(2002).An unusual organic-inorganic chain-like hybrid complex [(CuCl)(2)(o-phen)](infinity) (o-phen=o-phenanthroline).journal of solid state chemistry,167(2),402-406. |
| MLA | Wang ST,et al."An unusual organic-inorganic chain-like hybrid complex [(CuCl)(2)(o-phen)](infinity) (o-phen=o-phenanthroline)".journal of solid state chemistry 167.2(2002):402-406. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。