Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)]
文献类型:期刊论文
作者 | Lu SX ; Jin GX ; Hu NH |
刊名 | chinese journal of structural chemistry
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出版日期 | 2002 |
卷号 | 21期号:5页码:493-496 |
关键词 | CP-ASTERISK-RH HALFSANDWICH COMPLEXES ADDITION-REACTIONS LIGAND |
ISSN号 | 0254-5861 |
通讯作者 | jin gx |
中文摘要 | the crystal of complex [li(thf)(4)][fe(s2c2b10h10)(2)(thf)] 3 belongs to monoclinic, space group p2(1) with a = 11.964(2), b = 16.527(3), c = 12.554(3) angstrom,beta = 108.70(3)degrees, v= 2351.3(8) angstrom(3), z = 2, m-r = 835.95, d-c = 1.181 g/cm(3), mu (mokalpha) = 5.30 cm(-1), f(000) = '874, r = 0.0622 and rw 0.1538 for 1641 observed reflections with i > 2sigma(i). the ionic complex,of 3 contains the square pyramidal anion of [fe(s2c2b10h10)(2)(thf)](-) and the tetrahedral cation of [li(thf)(4)](+). the iron is 5-coordinated and located in the square pyramidal configuration. the iron atom and the four sulfur atoms are almost coplanar. the lithium atom is coordinated with four oxygen atoms of four thf molecules and located in a tetrahedral configuration. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000178238900008 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18323] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Lu SX,Jin GX,Hu NH. Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)][J]. chinese journal of structural chemistry,2002,21(5):493-496. |
APA | Lu SX,Jin GX,&Hu NH.(2002).Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)].chinese journal of structural chemistry,21(5),493-496. |
MLA | Lu SX,et al."Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)]".chinese journal of structural chemistry 21.5(2002):493-496. |
入库方式: OAI收割
来源:长春应用化学研究所
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