中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)]

文献类型:期刊论文

作者Lu SX ; Jin GX ; Hu NH
刊名chinese journal of structural chemistry
出版日期2002
卷号21期号:5页码:493-496
关键词CP-ASTERISK-RH HALFSANDWICH COMPLEXES ADDITION-REACTIONS LIGAND
ISSN号0254-5861
通讯作者jin gx
中文摘要the crystal of complex [li(thf)(4)][fe(s2c2b10h10)(2)(thf)] 3 belongs to monoclinic, space group p2(1) with a = 11.964(2), b = 16.527(3), c = 12.554(3) angstrom,beta = 108.70(3)degrees, v= 2351.3(8) angstrom(3), z = 2, m-r = 835.95, d-c = 1.181 g/cm(3), mu (mokalpha) = 5.30 cm(-1), f(000) = '874, r = 0.0622 and rw 0.1538 for 1641 observed reflections with i > 2sigma(i). the ionic complex,of 3 contains the square pyramidal anion of [fe(s2c2b10h10)(2)(thf)](-) and the tetrahedral cation of [li(thf)(4)](+). the iron is 5-coordinated and located in the square pyramidal configuration. the iron atom and the four sulfur atoms are almost coplanar. the lithium atom is coordinated with four oxygen atoms of four thf molecules and located in a tetrahedral configuration.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000178238900008
公开日期2010-11-03
源URL[http://202.98.16.49/handle/322003/18323]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Lu SX,Jin GX,Hu NH. Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)][J]. chinese journal of structural chemistry,2002,21(5):493-496.
APA Lu SX,Jin GX,&Hu NH.(2002).Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)].chinese journal of structural chemistry,21(5),493-496.
MLA Lu SX,et al."Synthesis and structure of iron complex with 1,2-dithiolate-1,2-dicarba-closo-dodecaborane [Li(THF)(4)][Fe(S2C2B10H10)(2)(THF)]".chinese journal of structural chemistry 21.5(2002):493-496.

入库方式: OAI收割

来源:长春应用化学研究所

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