中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Theoretical estimation of thermodynamic properties of the system PS/PPO on the basis of modified combining rule of Sanchez-Lacombe lattice fluid model

文献类型:期刊论文

作者Yang J ; An LJ ; Dong LS ; Teng FE ; Feng ZL
刊名european polymer journal
出版日期2002
卷号38期号:10页码:2083-2092
关键词POLY(2 POLYMER-SOLUTIONS POLY(VINYL METHYL-ETHER) NEUTRON-SCATTERING PHASE-SEPARATION BLENDS POLYSTYRENE DEPENDENCE BEHAVIOR COMPATIBILITY 6-DIMETHYL-1 4-PHENYLENE OXIDE)
ISSN号0014-3057
通讯作者an lj
中文摘要the three scaling parameters described in sanchez-lacombe lattice fluid theory (sllft), t*, p* and rho* of pure polystyrene (ps), pure poly(2,6-dimethyl-1,4-phenylene oxide) (ppo) and their mixtures are obtained by fitting corresponding experimental pressure volume-temperature data with equation-of-state of sllft. a modified combining rule in sllft used to match the volume per mer, v* of the ps/ppo mixtures was advanced and the enthalpy of mixing and flory-huggins (fh) interaction parameter were calculated using the new rule. it is found that the difference between the new rule and the old one presented by sanchez and lacombe is quite small in the calculation of the enthalpy of mixing and fh interaction parameter and the effect of volume-combining rule on the calculation of thermodynamic properties is much smaller than that of energy-combining rule. but the relative value of interaction parameter changes much due to the new volume-based combining rule. this effect can affect the position of phase diagram very much, which is reported elsewhere [macromolecules 34 (2001) 6291]
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000177434000023
公开日期2010-11-03
源URL[http://202.98.16.49/handle/322003/18381]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Yang J,An LJ,Dong LS,et al. Theoretical estimation of thermodynamic properties of the system PS/PPO on the basis of modified combining rule of Sanchez-Lacombe lattice fluid model[J]. european polymer journal,2002,38(10):2083-2092.
APA Yang J,An LJ,Dong LS,Teng FE,&Feng ZL.(2002).Theoretical estimation of thermodynamic properties of the system PS/PPO on the basis of modified combining rule of Sanchez-Lacombe lattice fluid model.european polymer journal,38(10),2083-2092.
MLA Yang J,et al."Theoretical estimation of thermodynamic properties of the system PS/PPO on the basis of modified combining rule of Sanchez-Lacombe lattice fluid model".european polymer journal 38.10(2002):2083-2092.

入库方式: OAI收割

来源:长春应用化学研究所

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