The nature of the interaction between polyaniline and 2,5-dimercapto-1,3,4-thiadiazole in electrochemical redox processes
文献类型：期刊论文
| 作者 | Wang P |
| 刊名 | journal of the electrochemical society
 |
| 出版日期 | 2002 |
| 卷号 | 149期号:9页码:a1171-a1174 |
| 关键词 | HIGH-ENERGY DENSITY ALL-SOLID-STATE POLYMERIZATION ELECTRODES LITHIUM BATTERIES THIN-FILM ELECTROLYTES OXIDATION |
| ISSN号 | 0013-4651 |
| 通讯作者 | wang p |
| 中文摘要 | the interaction between polyaniline (pan) and 2,5-dimercapto-1,3,4-thiadiazole (dmct) was investigated by means of cyclic voltammetry and uv-visible spectroscopy. the results show that the polymerization-depolymerization reaction of dmct or its dilithium salt li(2)dmct is a kinetically quasi-reversible process. pan exhibits very weak electrochemical activity in neutral propylene carbonate. after doping with protonic acid, such as hydrochloric acid or maleic acid etc., however, it shows an extensively enhanced electroactivity. for the complex system, pan-dmct or pan-li(2)dmct, polyaniline has no catalytic activity for the electrochemical polymerization-depolymerization reaction of dmct or dmct(2-). instead, the enhancement of the electrochemical redox activity of pan-dmct system compared with that of pan, dmct, li(2)dmct, and pan-li(2)dmct comes from the protonic doping of pan by dmct. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000177404600011 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18393]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang P. The nature of the interaction between polyaniline and 2,5-dimercapto-1,3,4-thiadiazole in electrochemical redox processes[J]. journal of the electrochemical society,2002,149(9):a1171-a1174. |
| APA | Wang P.(2002).The nature of the interaction between polyaniline and 2,5-dimercapto-1,3,4-thiadiazole in electrochemical redox processes.journal of the electrochemical society,149(9),a1171-a1174. |
| MLA | Wang P."The nature of the interaction between polyaniline and 2,5-dimercapto-1,3,4-thiadiazole in electrochemical redox processes".journal of the electrochemical society 149.9(2002):a1171-a1174. |
入库方式： OAI收割
来源：长春应用化学研究所
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