Systematic investigation of alkali metal ion transfer across the micro- and nano-water/1,2-dichloroethane interfaces facilitated by dibenzo-18-crown-6
文献类型：期刊论文
| 作者 | Yuan Y ; Shao YH |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2002 |
| 卷号 | 106期号:32页码:7809-7814 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS STEADY-STATE VOLTAMMOGRAMS LIQUID-LIQUID INTERFACES POTASSIUM-ION 1 DROPPING ELECTRODE TRANSFER RATES VOLTAMMETRY WATER KINETICS 2-DICHLOROETHANE INTERFACE |
| ISSN号 | 1520-6106 |
| 通讯作者 | shao yh |
| 中文摘要 | facilitated alkali metal ion (m+= li+, na+, k+, rb+, and cs+) transfers across the micro- and nano-water/1,2-dichloroethane (w/dce) interfaces supported at the tips of micro- and nanopipets by dibenzo-18-crown-6 (db18c6) have been investigated systematically using cyclic voltammetry. the theory developed by matsuda et al. was applied to estimate the association constants of db18c6 and m+ in the dce phase based on the experimental voltammetric results. the kinetic measurements for alkali metal ion transfer across the w/dce interface facilitated by db18c6 were conducted using nanopipets or-submicropipets, and the standard rate constants (k(0)) were evaluated by analysis of the experimental voltammetric data. they increase in the following order: k(cs+)(0) < k(li+)(0) < k(rb+)(0) < k(na+)(0) < k(k+)(0), which is in accordance with their association constants except cs+ and li+. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000177354000013 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18395]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan Y,Shao YH. Systematic investigation of alkali metal ion transfer across the micro- and nano-water/1,2-dichloroethane interfaces facilitated by dibenzo-18-crown-6[J]. journal of physical chemistry b,2002,106(32):7809-7814. |
| APA | Yuan Y,&Shao YH.(2002).Systematic investigation of alkali metal ion transfer across the micro- and nano-water/1,2-dichloroethane interfaces facilitated by dibenzo-18-crown-6.journal of physical chemistry b,106(32),7809-7814. |
| MLA | Yuan Y,et al."Systematic investigation of alkali metal ion transfer across the micro- and nano-water/1,2-dichloroethane interfaces facilitated by dibenzo-18-crown-6".journal of physical chemistry b 106.32(2002):7809-7814. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。