Electrochemiluminescence of tris(2,2 '-bipyridyl)ruthenium (II) ion-exchanged in polyelectrolyte-silica composite thin-films
文献类型：期刊论文
| 作者 | Wang HY ; Xu GB ; Dong SJ |
| 刊名 | electroanalysis
 |
| 出版日期 | 2002 |
| 卷号 | 14期号:12页码:853-857 |
| 关键词 | ELECTROGENERATED CHEMILUMINESCENCE RUTHENIUM COMPLEXES ECL REACTION ELECTRODES NAFION EMISSION AMINES |
| ISSN号 | 1040-0397 |
| 通讯作者 | dong sj |
| 中文摘要 | the organic-inorganic hybrid, pss-silica composite material was developed for the immobilization of tris(2,2'-bipyridyl)ruthenium(ii) (ru(bpy)(3)(2+)) on glassy carbon electrode via ion-exchange (pss stands for poly(sodium 4-styrene-sulfonate)). the electrochemiluminescence (ecl) and electrochemistry of ru(bpy)(3)(2-) immobilized in the composite thin films have been investigated with tripropylamine (tpa) as the coreactant. the immobilized ru(bpy)(3)(2-) underwent a surface process. the modified electrode was used for the ecl detection of tpa and showed high sensitivity. detection limit was 0,1 mumol l-1 for tpa (s/n = 3) with a linear range from 0.5 mumol l-1 to 5 mmol l-1 (r = 0.998), moreover, the resulting modified electrode was stable over six months and the good stability may be due to the strong interaction between ru(bpy)(3)(2-) and the high ion-exchange able pss-silica composite films on gce. compared with other materials. the pss-silica composite films containing incorporated ru(bpy)(3)(2-) showed improved sensitivity and long-term stability, thus, such composite thin film can be a promising material for the construction of ecl sensor. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000176936100008 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18437]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang HY,Xu GB,Dong SJ. Electrochemiluminescence of tris(2,2 '-bipyridyl)ruthenium (II) ion-exchanged in polyelectrolyte-silica composite thin-films[J]. electroanalysis,2002,14(12):853-857. |
| APA | Wang HY,Xu GB,&Dong SJ.(2002).Electrochemiluminescence of tris(2,2 '-bipyridyl)ruthenium (II) ion-exchanged in polyelectrolyte-silica composite thin-films.electroanalysis,14(12),853-857. |
| MLA | Wang HY,et al."Electrochemiluminescence of tris(2,2 '-bipyridyl)ruthenium (II) ion-exchanged in polyelectrolyte-silica composite thin-films".electroanalysis 14.12(2002):853-857. |
入库方式： OAI收割
来源：长春应用化学研究所
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