Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion
文献类型：期刊论文
| 作者 | Yuan M ; Li YG ; Wang E ; Lu Y ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of the chemical society-dalton transactions
 |
| 出版日期 | 2002 |
| 期号 | 14页码:2916-2920 |
| 关键词 | STATE COORDINATION CHEMISTRY CHARGE-TRANSFER SALTS MAGNETIC-PROPERTIES WATER-MOLECULES X-RAY CLUSTERS CHAINS CO NI |
| ISSN号 | 1472-7773 |
| 通讯作者 | wang e |
| 中文摘要 | an unusual composite hybrid material [co-4 (phen)(8) (h2o)(2) (hpo3)(2)](h3o)(3) [pmo8vi v-4(iv) o-40 ((vo)-o-iv) 2] 1 (phen = 1,10-phenanthroline) has been hydrothermally synthesized from a mixture of nh4vo3, na2moo4.2h(2)o, cocl2.6h(2)o, phen, h3po3 and water. it was characterized by elemental analysis, ir, uv-vis, xps, epr, tg and single crystal x-ray diffraction. the title compound is constructed from the organic-inorganic hybrid [co-4(phen)(8)(h2o)(2) (hpo3)(2)](4+) and highly reduced bi-capped pseudo-keggin [(pmo8v4o40)-v-vi-o-iv ((vo)-o-iv)(2)](7-) polyoxoanions the structure exhibits an extended 2d network through hydrogen bonds among cations, anions and h2o, combining polyoxometalates with metal phosphonates for the first time. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000176822000024 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18455]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan M,Li YG,Wang E,et al. Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion[J]. journal of the chemical society-dalton transactions,2002(14):2916-2920. |
| APA | Yuan M.,Li YG.,Wang E.,Lu Y.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion.journal of the chemical society-dalton transactions(14),2916-2920. |
| MLA | Yuan M,et al."Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion".journal of the chemical society-dalton transactions .14(2002):2916-2920. |
入库方式： OAI收割
来源：长春应用化学研究所
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