A novel one-dimensional manganese phosphomolybdate with rectangular cavities: [H3N(CH2)(4)NH3] (H3O)(2){[Mn(phen)(2)](4) [(MnMo12O30)-O-v(HPO4)(6)(H2PO4)2} center dot 4H(2)O
文献类型:期刊论文
作者 | Yuan M ; Wang EB ; Lu Y ; Li YG ; Hu CW ; Hu NH ; Jia HQ |
刊名 | inorganic chemistry communications
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出版日期 | 2002 |
卷号 | 5期号:7页码:505-508 |
关键词 | MOLYBDENUM PHOSPHATE HYDROTHERMAL SYNTHESIS TUNNEL |
ISSN号 | 1387-7003 |
通讯作者 | wang eb |
中文摘要 | a novel manganese phosphomolybdate, [h3n(ch2)(4)nh3](h3o)(2){[mn(phen)(2)](4)[(mnmovo30)-o-12(hpo4)(6)(h2po4)(2)]} . 4h(2)o 1, has been hydrothermally synthesized and structurally characterized by single crystal x-ray diffraction. the crystal data: triclinic, p (1) over bar, a = 14.172(7) angstrom, b = 16.547(2) angstrom, c = 16.679(3) angstrom, alpha = 62.881(12)degrees, beta = 73.83(3)degrees, gamma = 88.81(3)degrees. x-ray crystallography shows that the [mn(phen)(2)] fragments are covalently bonded to the [mn(mo6p4)(2)] dimers leading to a one-dimensional chain with rectangular cavities occupied by tetramethylene-diamine cations and water molecules. (c) 2002 elsevier science b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000176797300014 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18461] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Yuan M,Wang EB,Lu Y,et al. A novel one-dimensional manganese phosphomolybdate with rectangular cavities: [H3N(CH2)(4)NH3] (H3O)(2){[Mn(phen)(2)](4) [(MnMo12O30)-O-v(HPO4)(6)(H2PO4)2} center dot 4H(2)O[J]. inorganic chemistry communications,2002,5(7):505-508. |
APA | Yuan M.,Wang EB.,Lu Y.,Li YG.,Hu CW.,...&Jia HQ.(2002).A novel one-dimensional manganese phosphomolybdate with rectangular cavities: [H3N(CH2)(4)NH3] (H3O)(2){[Mn(phen)(2)](4) [(MnMo12O30)-O-v(HPO4)(6)(H2PO4)2} center dot 4H(2)O.inorganic chemistry communications,5(7),505-508. |
MLA | Yuan M,et al."A novel one-dimensional manganese phosphomolybdate with rectangular cavities: [H3N(CH2)(4)NH3] (H3O)(2){[Mn(phen)(2)](4) [(MnMo12O30)-O-v(HPO4)(6)(H2PO4)2} center dot 4H(2)O".inorganic chemistry communications 5.7(2002):505-508. |
入库方式: OAI收割
来源:长春应用化学研究所
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