Hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)(3)](2)[(SiMo10V2O40)-O-IV((VO)-O-IV)2]center dot 2H(2)O
文献类型：期刊论文
| 作者 | Luan GY ; Li YG ; Wang EB ; Han ZB ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | inorganic chemistry communications
 |
| 出版日期 | 2002 |
| 卷号 | 5期号:7页码:509-511 |
| 关键词 | COORDINATED WATER-MOLECULES POLYOXOMETALATE CHEMISTRY KEGGIN HETEROPOLYVANADATE POLYOXOANION POLYANION CLUSTERS CHAIN |
| ISSN号 | 1387-7003 |
| 通讯作者 | wang eb |
| 中文摘要 | a novel compound [ni(phen)(3)](2)[(simo10v1/2o40)-o-v((vo)-o-iv)(2)] . 2h(2)o has been hydrothermally synthesized and structurally characterized by single-crystal x-ray diffraction. the compound crystallizes in the triclinic, system, space group p-1, a = 12.378(4) angstrom, b = 14.148(5) angstrom, c = 14.316(2) angstrom, alpha = 105.91(2)degrees, beta = 95.31(2)degrees, gamma = 96.89(3)degrees, v = 2373.0(12) angstrom(3), z = 1, (lambdamo(kalpha)) = 0.71073 angstrom, r1 (wr2) = 0.0869(0.2174). data were collected on a siemens p4 four-circle diffractometer at 293 k in the range of 1.51 < theta < 22.50degrees using the omega-scan technique. empirical absorption correction (psi scan) was applied. the structure was solved by the direct method and refined by the full-matrix least-squares on f-2 using the shelxl-97 software. x-ray crystallographic study showed that the title compound contained a bi-capped alpha-kegin-type [(simo10v2o40)-o-iv((vo)-o-iv)(2)](4-) polyoxoanion. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000176797300015 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18463]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Luan GY,Li YG,Wang EB,et al. Hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)(3)](2)[(SiMo10V2O40)-O-IV((VO)-O-IV)2]center dot 2H(2)O[J]. inorganic chemistry communications,2002,5(7):509-511. |
| APA | Luan GY.,Li YG.,Wang EB.,Han ZB.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)(3)](2)[(SiMo10V2O40)-O-IV((VO)-O-IV)2]center dot 2H(2)O.inorganic chemistry communications,5(7),509-511. |
| MLA | Luan GY,et al."Hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)(3)](2)[(SiMo10V2O40)-O-IV((VO)-O-IV)2]center dot 2H(2)O".inorganic chemistry communications 5.7(2002):509-511. |
入库方式： OAI收割
来源：长春应用化学研究所
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