Preparation and characterization of poly(ethyl acrylate)/bentonite nanocomposites by in situ emulsion polymerization
文献类型：期刊论文
| 作者 | Tong X ; Zhao HC ; Tang T ; Feng ZL ; Huang BT |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 40期号:11页码:1706-1711 |
| 关键词 | CLAY HYBRID COMPOSITE LAYERED SILICATES INTERCALATION |
| ISSN号 | 0887-624x |
| 通讯作者 | tang t |
| 中文摘要 | transparent poly(ethyl acrylate) (pea)/bentonite nanocomposites containing intercalated-exfoliated combinatory structures of clay were synthesized by in situ emulsion polymerizations in aqueous dispersions containing bentonite. the samples for characterization were prepared through direct-forming films of the resulting emulsions without coagulation and separation. an examination with x-ray diffraction and transmission electron microscopy showed that intercalated and exfoliated structures of clay coexisted in the pea/bentonite nanocomposites. the measurements of mechanical properties showed that pea properties were greatly improved, with the tensile strength and modulus increasing from 0.65 and 0.24 to 11.16 and 88.41 mpa, respectively. dynamic mechanical analysis revealed a very marked improvement of the storage modulus above the glass-transition temperature. in addition, because of the uniform dispersion of silicate layers in the pea matrix, the barrier properties of the materials were dramatically improved. the permeability coefficient of water vapor decreased from 30.8 x 10(-6) to 8.3 x 10(-6) g cm/cm(2)s cmhg. (c) 2002 wiley periodicals, inc. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000175550700005 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18609]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tong X,Zhao HC,Tang T,et al. Preparation and characterization of poly(ethyl acrylate)/bentonite nanocomposites by in situ emulsion polymerization[J]. journal of polymer science part a-polymer chemistry,2002,40(11):1706-1711. |
| APA | Tong X,Zhao HC,Tang T,Feng ZL,&Huang BT.(2002).Preparation and characterization of poly(ethyl acrylate)/bentonite nanocomposites by in situ emulsion polymerization.journal of polymer science part a-polymer chemistry,40(11),1706-1711. |
| MLA | Tong X,et al."Preparation and characterization of poly(ethyl acrylate)/bentonite nanocomposites by in situ emulsion polymerization".journal of polymer science part a-polymer chemistry 40.11(2002):1706-1711. |
入库方式： OAI收割
来源：长春应用化学研究所
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